2023
DOI: 10.1039/d2fd00090c
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Radiative cooling in silver and palladium doped gold clusters

Abstract: The emission of photons from a thermally populated electronic excited state, via the process of recurrent fluorescence, has been recognized as a prominent cooling channel in hot molecules and small...

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“…Very recently, odd–even oscillations between open-closed electronic subshell configurations were also found to affect radiation cooling rates of Au clusters (and Au–Ag and Au–Pd binary nanoalloys). 93 This effect could help stabilise particular multi-metallic cluster configurations in out-of-equilibrium gas-phase synthesis.…”
Section: Instrumentation Development Responsesmentioning
confidence: 99%
“…Very recently, odd–even oscillations between open-closed electronic subshell configurations were also found to affect radiation cooling rates of Au clusters (and Au–Ag and Au–Pd binary nanoalloys). 93 This effect could help stabilise particular multi-metallic cluster configurations in out-of-equilibrium gas-phase synthesis.…”
Section: Instrumentation Development Responsesmentioning
confidence: 99%