2021
DOI: 10.1002/slct.202101323
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Rare cis‐Dioxido Uranyl Framework Crystalline Complexes: Synthesis, Structure, Characterization and Properties

Abstract: The trans-dioxido uranyl frameworks named as [(UO 2 )(Aip)(DMA)] (1), H[(UO 2 )(Aib) 3 ] (2) and rare cis-dioxido [(UO 2 )Co(Suc) 2 (H 2 O) 4 ] (3), and [(UO 2 )Ni(Suc) 2 (H 2 O) 4 ] (4) have been synthesized, which based on 5-aminoisophthalic acid (H 2 Aip), 3-aminobenzoic acid (HAib), and succinic acid (H 2 Suc) as ligands. They were characterized by Fourier Transform Infrared spectra, UV-vis absorption spectra, single-crystal X-ray diffraction, powder X-ray diffraction and thermogravimetry analysis. It was … Show more

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