Reaction kinetics in reactive extraction for chiral separation of α-cyclohexyl-mandelic acid enantiomers with hydroxypropyl-β-cyclodextrin

Chiral separation of α-cyclohexylmandelic acid enantiomers using ionic liquid/salt aqueous two-phase system

“…This was a better enantioselectivity than that of the PEG-based ATPS (Li & Li, 2012). Although the outcome is no better than those of the O/W-based system (Tang et al, 2007b(Tang et al, , 2011 and ethanol-based ATPS (Guo et al, 2011), it exhibited the potential for the enantioseparation of other chiral compounds as a more environmentally benign system. If some other appropriate chiral selectors are selected, there Brought to you by | New York University Bobst Library Technical Services Authenticated Download Date | 10/6/15 7:07 AM may be better enantioseparation in the programmable ILATPS.…”

“…Hence, researchers have devoted themselves to finding effective ways by which mass enantiomerically pure compounds can be obtained. The liquid-liquid extraction system has attracted attention in view of its potential for scaling-up (Schuur et al, 2010(Schuur et al, , 2011Tang et al, 2007aTang et al, , 2007bTang et al, , 2011Sunsandee et al, 2013).…”

The mechanism of interphase mass transfer reaction and precipitation process of HDEHP–TBP–Cu–CCl4/H2C2O4–H2O system

“…One of the most promising methods to remove the copper is extraction-stripping-precipitation method, which was also used in the research [4] to separate specific metal ions or pollutants, and was widely used in nuclear industry [5]. In addition, the method that using Lewis mass transfer cell for liquid-liquid reactive extraction was also widely used in the research on chiral separation, as reported by Tang et al [6,7], Steensma et al [8] and Tang et al [9]. Inter-phase process of liquid-liquid system is the main factor that influences the rate of mass transfer reaction.…”

Kinetics study on the reactive extraction of homophenylalanine enantiomers with BINAP-copper complex

“…The extraction kinetics of some reactive extraction systems has been reported (28,29). The theory of extraction accompanied by a chemical reaction was successfully applied for their investigation and provides a powerful tool for the kinetics study.…”