Reactions of dithioxo-1,3,2?5,4?5-dithiadiphosphetanes with antimony(III) alkoxides

Низамов, И. С.; Matseevskii, Alexey V.; Батыева, Э. С.; Azancheev, N. M.; Vandyukova, I. I.; Shagidullin, R. R.

doi:10.1002/(sici)1098-1071(1999)10:5<399::aid-hc10>3.0.co;2-z

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Differing Coordination Modes of (O‐Alkyl)‐p‐Ethoxyphenyldithiophosphonato Ligands in Copper(I), Silver(I) and Gold(I) Triphenylphosphine Complexes

Haiduc¹,

Mezei²,

Micu-Semeniuc³

et al. 2005

Zeitschrift anorg allge chemie

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The three (O‐methyl)‐p‐ethoxyphenyldithiophosphonato triphenylphosphine complexes of copper, silver and gold, [(Ph3P)nM{S2P(OMe)C6H4OEt‐p}] (M = Cu, n = 2; M = Ag, Au, n = 1) investigated structurally by X‐ray diffraction exhibit remarkable structural differences. The copper compound is a four‐coordinate chelate monomer with Cu–S 2.4417(6) and 2.5048(6) Å; P–Cu–S 104.24(2)–114.01(2)°; Cu–S–P 82.49(3)° and 80.85(2)°. The silver compound is a cyclic dimer with bridging dithiophosphonato ligands and three‐coordinate silver atoms [Ag–S 2.5371(5) and 2.6867(5) Å; P–Ag–S 122.88(2)° and 122.17(2)°; Ag–S–P 89.32(2)° and 103.56(2)°]. The gold compound is monomeric with linear dicoordinate gold [Au–S 2.3218(6) Å; P–Au–S 177.72(2)°, Au–S–P 100.97(3)°].

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