Réactivité du trioxyde de chlore avec des chlorures, des nitrates, des carbonates et des perchlorates hydratés. Synthèse et analyse structurale de complexes de Cd(II) et Hg(II): Cd(ClO₄)₂, Hg(ClO₄)₂, ClO₂Cd(ClO₄)₃, NO₂Cd(ClO₄)₃, (NO₂)₂Hg(ClO₄)₄ et HgClClO₄

Reactions of ClF3 with Main Group and Transition Metal Oxides: Access to Dioxychloronium(V) Fluoridometallates and Oxidofluoridometallates

“…The experimental and calculated vibrational frequencies are listed in Table 8. Similar vibrational frequencies were reported for [ClO 2 ] + in compounds such as [ClO 2 ][GeF 5 ], [ClO 2 ][ M F 6 ] ( M =Ru, Pt, Au, Sb), [ClO 2 ][ClO 4 ], [ClO 2 ][Cd(ClO 4 ) 3 ], [ClO 2 ][Au(ClO 4 ) 4 ] and [ClO 2 ][ M (ClO 4 ) 4 ] ( M =In, Tl) [34,37,40,42,43,115–118] . This indicates a minor effect of the anions and bridging atoms (O or F) on the vibrational frequencies of the [ClO 2 ] + cation.…”

“…The experimental and calculated vibrational frequencies are listed in . [34,37,40,42,43,[115][116][117][118] This indicates a minor effect of the anions and bridging atoms (O or F) on the vibrational frequencies of the ] (M = As, Ir) are similar to those of respective Li + salts, albeit with more bands due to lower symmetry of the [MF 6 ] À anion. [120,121] [122] The Raman spectrum is otherwise similar to the reported one of [ClO 2 ] 2 [SnF 6 ], which itself has too many bands for [a] μ-Bridging between M atoms.…”