2024
DOI: 10.1002/anie.202412622
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Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable

Leonidas‐Dimitrios Syntrivanis,
Konrad Tiefenbacher

Abstract: There is increasing interest in the discovery and application of molecular flasks ‐ supramolecular host structures capable of catalyzing organic reactions. Reminiscent of enzymes due to possessing a host cavity akin to an active site, molecular flasks can exhibit complex catalytic mechanisms and in many cases provide selectivity not achievable in bulk solvent. In this Review, we aim to organize the increasingly diverse examples through a two‐part structure. In part one, we provide an overview of the different … Show more

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