Recent advances in silicon-based composite anodes modified by metal-organic frameworks and their derivatives for lithium-ion battery applications

Ou, Hong; Peng, Yanhua; Sang, Xiaoyan; Zhong, Hua; Zhou, Jian‐En; Lin, Xiaoming; Reddy, R. Chenna Krishna; Ma, Guozheng; Wu, Yi-nan

doi:10.1016/j.jallcom.2023.170713

Cited by 16 publications

(7 citation statements)

References 118 publications

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“…Finally, the matrix's built-in open channels are advantageous for Li + transportation and facilitate rate performance. 7 In 2015, Han prepared a multilayer sandwich design in which a layer of Super P (SP) & binder was applied to a Cu current collector, followed by a layer of Si, followed by a layer of MOF. 11 The authors reported a relatively stable areal capacity of 600 μAh cm −2 for an SP-nano Si-MOF anode.…”

Section: Introductionmentioning

confidence: 98%

“…They can adopt a variety of different structures depending on the type of metal ion (Co, Zn, Cu, Al, etc.) and linker . MOFs have been investigated in numerous fields and are particularly well-suited for applications that require a high surface area, such as gas adsorption and separation, biological applications, and catalysis .…”

Section: Introductionmentioning

confidence: 99%

“…Moreover, the uniformly distributed metal centers within the porous carbon structure could enhance the electrode conductivity and improve the storage capacity. Finally, the matrix’s built-in open channels are advantageous for Li + transportation and facilitate rate performance …”

Section: Introductionmentioning

confidence: 99%

“…and linker. 7 MOFs have been investigated in numerous fields and are particularly well-suited for applications that require a high surface area, such as gas adsorption and separation, 8 biological applications, 9 and catalysis. 10 For Li-ion batteries, MOFs have been involved in two main design strategies: a multilayer sandwich design and an encapsulation design where the MOF surrounds the silicon (Si@MOF).…”

Section: Introductionmentioning

confidence: 99%

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Critical Investigation of Metal–Organic-Frameworks to Improve the Silicon Anode of Lithium-Ion Batteries

Sturman,

Houache,

do Pim

et al. 2023

ACS Appl. Energy Mater.

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The poor capacity retention of the silicon (Si) anode has hindered its widespread use in lithium-ion batteries. Metal− organic-frameworks (MOF) may offer the structural and functional tunability needed to alleviate some of the longstanding problems associated with silicon pulverization. Herein, MOF-74 (Co-based) and were implemented in different design configurations for high-Si loading electrodes. Multilayer sandwich configurations provided a modest improvement in capacity retention. However, greatest improvements in capacity retention were observed when the MOF was in situ synthesized onto the silicon surface (Si@ MOF) and subsequently pyrolyzed. The best performing high-loading 0.5Si@MOF-c sample delivered a high capacity of 1000 mAh/g and retained 60% capacity after 100 cycles, surpassing a standard silicongraphite composite.

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Section: Introductionmentioning

confidence: 98%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Critical Investigation of Metal–Organic-Frameworks to Improve the Silicon Anode of Lithium-Ion Batteries

Sturman,

Houache,

do Pim

et al. 2023

ACS Appl. Energy Mater.

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“…Metal-organic frameworks (MOFs), a class of crystalline porous organic-inorganic materials with distinctive physical and chemical properties, composed of organic ligands with coordinated selfassembled bonds and metal ions. It has been widely applied for various applications in many industries such as catalysis [1], gas storage, gas separation [2], lithium-ion batteries [3], supercapacitors [4], and electrochemical sensors [5]. Due to its easily modifiable structure, good chemical stability, high surface area, and low density, MOFs has received the majority of attention to date.…”

Section: Introductionmentioning

confidence: 99%

Preparation of manganese-based metal organic framework (MOF) and its characterization properties

Shamsul,

Muslihati,

Zaid

2024

J. Phys.: Conf. Ser.

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Metal-organic frameworks (MOFs) are produced by the reaction of metal ions and organic linkers with extremely crystalline and porous coordination networks. The applications of MOF cover from gas purification, gas separation, catalysis and super-capacitors. This work reports on the synthesization of metal-organic framework (MOF), using mangan (II) nitrate tetrahydrate as source of metal ions, 2-methylimidazole as organic ligand and ethanol as solvent. The material was prepared using precipitation method, at room temperature for 48 hours. The characterization of this material were carried out including X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The SEM analysis shows an irregular structure with a few petals. XRD shows several peaks, indicating crystallinity of the material, and amorphous state. To study the electrochemical property of the material, Cyclic Voltammetry (CV) was conducted. The cyclic voltammetry result shows peak at 0.23 V, with current output of 0.14 μA, with no changes in peak position as the scanning rate increases from 10 to 100 mV/s.

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Bio‐Inspired Electrodes with Rational Spatiotemporal Management for Lithium‐Ion Batteries

Song,

Li,

Gao

et al. 2024

Advanced Science

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Lithium‐ion batteries (LIBs) are currently the predominant energy storage power source. However, the urgent issues of enhancing electrochemical performance, prolonging lifetime, preventing thermal runaway‐caused fires, and intelligent application are obstacles to their applications. Herein, bio‐inspired electrodes owning spatiotemporal management of self‐healing, fast ion transport, fire‐extinguishing, thermoresponsive switching, recycling, and flexibility are overviewed comprehensively, showing great promising potentials in practical application due to the significantly enhanced durability and thermal safety of LIBs. Taking advantage of the self‐healing core–shell structures, binders, capsules, or liquid metal alloys, these electrodes can maintain the mechanical integrity during the lithiation–delithiation cycling. After the incorporation of fire‐extinguishing binders, current collectors, or capsules, flame retardants can be released spatiotemporally during thermal runaway to ensure safety. Thermoresponsive switching electrodes are also constructed though adding thermally responsive components, which can rapidly switch LIB off under abnormal conditions and resume their functions quickly when normal operating conditions return. Finally, the challenges of bio‐inspired electrode designs are presented to optimize the spatiotemporal management of LIBs. It is anticipated that the proposed electrodes with spatiotemporal management will not only promote industrial application, but also strengthen the fundamental research of bionics in energy storage.

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Recent advances in silicon-based composite anodes modified by metal-organic frameworks and their derivatives for lithium-ion battery applications

Cited by 16 publications

References 118 publications

Critical Investigation of Metal–Organic-Frameworks to Improve the Silicon Anode of Lithium-Ion Batteries

Critical Investigation of Metal–Organic-Frameworks to Improve the Silicon Anode of Lithium-Ion Batteries

Preparation of manganese-based metal organic framework (MOF) and its characterization properties

Bio‐Inspired Electrodes with Rational Spatiotemporal Management for Lithium‐Ion Batteries

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