Recent advances in synthesis and properties of silver nanoclusters

Liu, Xiaolin; Ki, Taeyoung; Deng, Guocheng; Yoo, Seungwoo; Lee, Kangjae; Lee, Byoung-Hoon; Hyeon, Taeghwan; Bootharaju, Megalamane S.

doi:10.1039/d4nr01788a

Nanoscale

2024

DOI: 10.1039/d4nr01788a

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Recent advances in synthesis and properties of silver nanoclusters

Xiaolin Liu,

Taeyoung Ki,

Guocheng Deng

et al.

Abstract: This minireview outlines recent progress in synthetic strategies, photophysical, surface reactivity, and catalytic properties of Ag(0)-containing ligand-protected atomically precise silver nanoclusters.

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2024

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Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

Sheng,

Han,

Wang

et al. 2024

Angewandte Chemie

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The established capability of anion templates in precisely manipulating the size, geometry, and function of metal clusters is well acknowledged. However, the development of a systematic methodology for orchestrating the assembly of silver clusters, particularly those encompassing multiple distinct types of anion templates, remains elusive due to the formidable synthetic challenge. In this work, we report two novel silver clusters, Ag57 and Ag72, using two and three different anion templates, respectively. Ag57 features a gyroscope‐like monovalent cation with an Ag3 triangle core sandwiched by one [SiW9O34]10− and a triad of Cl− anion templates. By intentionally introducing the third anion template, SO42−, the structure is expanded to the unprecedented Ag72 (with 15 silver atoms epitaxially grown on top of Ag57) resembling a tumbler, inside of which two Ag3 layers are laminated by one [SiW9O34]10−, seven Cl− and one SO42− anion templates in parallel with respect to longitudinal orientation. It is noteworthy that Ag72 exhibits remarkable structural complexity and represents a pioneering achievement as the first silver cluster incorporating three distinct types of anion templates. In addition, Ag72 demonstrates a significant advantage over Ag57, particular in terms of applications such as luminescent thermometers and remote laser ignition.

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Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

Sheng,

Han,

Wang

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

Sheng,

Han,

Wang

et al. 2024

Angew Chem Int Ed

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Recent advances in synthesis and properties of silver nanoclusters

Abstract: This minireview outlines recent progress in synthetic strategies, photophysical, surface reactivity, and catalytic properties of Ag(0)-containing ligand-protected atomically precise silver nanoclusters.

Cited by 2 publications

References 133 publications

Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates

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