Recent Advances in the Synthesis and Transformations of Heterocycles Mediated by Fluoride Ion Activated Organosilicon Compounds

Lukevics, É.; Абеле, Э.

doi:10.3987/rev-01-545

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Cited by 15 publications

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Nucleophilic Additions of Perfluoroalkyl Groups

Beier

Zibinsky²,

Prakash

2016

Organic Reactions

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The trifluoromethyl and perfluoroalkyl functional groups possess significant thermal, chemical, and metabolic stability, as well as high lipophilicity and electronegativity. These physicochemical properties render fluorinated carbon residues indispensable in diverse applications, such as agrochemistry, drug design, and material chemistry. The generation and properties of nucleophilic perfluoroalkyl reagents as well as the scope and limitations of their additions to various electrophilic partners is described in this chapter.

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