Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts

Shimada, Shigeru

doi:10.1007/3418_2023_99

Topics in Organometallic Chemistry

2023

DOI: 10.1007/3418_2023_99

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Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts

Shigeru Shimada

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2024

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Cited by 2 publications

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Prospects in Sustainable Hydrosilylation by Biphase Catalysis

Goncharova,

Beletskaya,

Arzumanyan

2024

ChemCatChem

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This concept addresses the main economic, environmental, scientific and technological issues associated with the use of homogeneous Pt‐catalysts in the important industrial hydrosilylation process. The development of biphase catalysis is proposed as the most promising approach. One solution we suggest is the use of ethylene glycol (EG) as a medium in biphase catalysis. We have previously shown that EG in Pt‐catalyzed hydrosilylation serves not only as a medium but also as a mild reducing agent of Pt‐ions to Pt0, as well as an effective ligand for the preparation of mononuclear Pt01‐complexes. These zero valent platinum complexes are single‐atom catalysts (SAC) and have high activity in hydrosilylation, stability during storage and the ability to be recycled multiple times (~40 times). This option of using an atomic catalyst allows us to combine the advantages of homogeneous and heterogeneous catalysts.

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Prospects in Sustainable Hydrosilylation by Biphase Catalysis

Goncharova,

Beletskaya,

Arzumanyan

2024

ChemCatChem

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Co/Fe Dual Catalysis for Sequential Hydrosilylation–Isomerization: Access to Trisubstituted (E)‐Alkenyl Silanes from Terminal Alkynes

Guo,

Liu,

Huang

2024

Chin. J. Chem.

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Comprehensive SummaryBy rational modification of electronic and steric properties of pincer ligands, a Co/Fe dual catalyst system is developed for one‐pot sequential Markovnikov alkyne hydrosilylation and stereoselective alkene isomerization. The protocol provides an atom‐economical and efficient approach to trisubstituted (E)‐alkenyl silanes from widely accessible terminal alkynes with high regio‐ and stereoselectivities under mild conditions. The utility of this reaction was demonstrated by gram‐scale synthesis and derivatization of bioactive molecules. The radical clock and trapping experiments indicated that radical pathway might be operative in the alkene isomerization step.

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Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts

Cited by 2 publications

References 374 publications

Prospects in Sustainable Hydrosilylation by Biphase Catalysis

Prospects in Sustainable Hydrosilylation by Biphase Catalysis

Co/Fe Dual Catalysis for Sequential Hydrosilylation–Isomerization: Access to Trisubstituted (E)‐Alkenyl Silanes from Terminal Alkynes

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