Recent progress in catalytic deoxygenation of biomass pyrolysis oil using microporous zeolites for green fuels production

Naqvi, Salman Raza; Khoja, Asif Hussain; Ali, Imtiaz; Naqvi, Muhammad; Nооr, Tayyaba; Ahmad, Awais; Luque, Rafael; Amin, Nor Aishah Saidina

doi:10.1016/j.fuel.2022.126268

Cited by 54 publications

(19 citation statements)

References 127 publications

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“…142 It is an unstable liquid with full of oxygen-containing compounds such as carboxylic acids, phenolics, esters, etc., and was initially supposed to replace vehicle fuels. [143][144][145] However, due to its low fuel properties like low heating value, high water content, high acid content, low stability, etc., it cannot be used directly as an engine fuel. [146][147][148] Therefore, its upgrading is required.…”

Section: Biorefinery Based On the Thermochemical Treatmentcommercial ...mentioning

confidence: 99%

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A review on thermochemical based biorefinery catalyst development progress

Gholizadeh,

Castro,

Fabrega

et al. 2023

Sustainable Energy Fuels

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Section: Biorefinery Based On the Thermochemical Treatmentcommercial ...mentioning

confidence: 99%

“…, and was initially supposed to replace vehicle fuels. 143–145 However, due to its low fuel properties like low heating value, high water content, high acid content, low stability, etc. , it cannot be used directly as an engine fuel.…”

Section: Biorefinery Based On the Thermochemical Treatment-commercial...mentioning

confidence: 99%

A review on thermochemical based biorefinery catalyst development progress

Gholizadeh,

Castro,

Fabrega

et al. 2023

Sustainable Energy Fuels

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show abstract

“…The use of pyrolysis may have various benefits. Oil yields obtained via pyrolysis may be greater than those obtained using more conventional means [102,103] . During the pyrolysis process, bio‐oil is produced, which can then be refined into biodiesel [104,105] .…”

Section: Biodiesel Production Pathwaysmentioning

confidence: 99%

“…Oil yields obtained via pyrolysis may be greater than those obtained using more conventional means. [102,103] During the pyrolysis process, bio-oil is produced, which can then be refined into biodiesel. [104,105] Capturing the heat released during pyrolysis and putting it to productive use is one way to increase the energy efficiency of the biodiesel production process as a whole.…”

Section: Pyrolysismentioning

confidence: 99%

A Review on Biodiesel Production, Analysis, and Emission Characteristics from Non‐Edible Feedstocks

Jamil

2023

ChemistrySelect

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Biodiesel produced from different edible and non‐edible feedstocks is a viable alternative option for fueling a combustion engine. However, the widespread use of edible sources for biodiesel production may lead to food versus fuel controversy. Oil from non‐edible feedstock is best possible solution for problems that inhibits biodiesel production on commercial scale. This study presents the potential of different non‐edible feedstock for biodiesel production. Several aspects such as extraction technologies used for extracting oil from non‐edible sources and biodiesel production pathways from non‐edible feedstocks are discussed. The quality of biodiesel should be assured before its commercialization by different physical and chemical characterization techniques are used. In particular, the emission comparison of biodiesel derived from the different non‐edible feedstocks is discussed. Based on this study, the non‐edible feedstocks have the potential to produce biodiesel but still it has a long way to go. This is due to non‐edible feedstock is in the R&D phase and needs more research to eliminate additional treatment steps compared to edible feedstock for economic aspects. Furthermore, there has been a trade off in emission properties of biodiesels produced from non‐edible feedstocks which must be removed or evaluated for pilot scale investigations before commercialization.

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“…35 The production of primary petrochemicals from biomassderived chemical platforms bearing oxygen-containing functionalities requires extensive deoxygenation. 36 Bio-oil, produced by the thermal deconstruction of biomolecules under pyrolytic conditions, is often used as the starting material for further deoxygenation into hydrocarbon fuels and chemicals in the presence of a suitable catalyst candidate. 37 Bio-oil is typically used as fuels after stabilization and suitable upgrading (e.g., catalytic deoxygenation).…”

Section: Introductionmentioning

confidence: 99%

Sustainable Synthesis of Drop-In Chemicals from Biomass via Chemical Catalysis: Scopes, Challenges, and the Way Forward

Dutta

2023

Energy Fuels

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A handful of small organics, namely, ethylene, propylene, butadiene, benzene, toluene, xylenes, and methanol, produced from petroleum and other fossilized carbon-based resources, can produce practically all petrochemicals and synthetic organic polymers used in the industrialized societies. The molecules mentioned above, often referred to as primary petrochemicals, must be sourced from renewable carbon feedstock to achieve the long-aspired all-around sustainability in chemical manufacturing. Significant efforts have been devoted to developing efficient chemical–catalytic pathways for selectively converting biomolecules and biopolymers into these petroleum-derived chemical platforms. The processes take advantage of prevalent petrorefinery infrastructure, well-documented synthetic value addition pathways of the chemical platforms, and established markets of the derived products. Relative merits and demerits of various catalytic routes in producing the aforementioned primary petrochemicals from renewable biomass have been deliberated. This review elaborates on the synthetic methodologies available for synthesizing the drop-in replacement of primary petrochemical from renewable biomass, focusing on process selectivity, feedstock selection, and catalyst performance. The critical analyses presented in this review will assist in appraising the research accomplishments to date, identifying the bottlenecks, and realigning the future perspectives.

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Recent progress in catalytic deoxygenation of biomass pyrolysis oil using microporous zeolites for green fuels production

Cited by 54 publications

References 127 publications

A review on thermochemical based biorefinery catalyst development progress

A review on thermochemical based biorefinery catalyst development progress

A Review on Biodiesel Production, Analysis, and Emission Characteristics from Non‐Edible Feedstocks

Sustainable Synthesis of Drop-In Chemicals from Biomass via Chemical Catalysis: Scopes, Challenges, and the Way Forward

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