Recent Progress in Fabrication and Application of BN Nanostructures and BN-Based Nanohybrids

Shtansky, Dmitry V.; Matveev, Andrei T.; Permyakova, Elizaveta S.; Leybo, Denis V.; Konopatsky, Anton S.; Сорокин, Павел Б.

doi:10.3390/nano12162810

Cited by 43 publications

(17 citation statements)

References 341 publications

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“…Hexagonal boron nitride ( h -BN) nanomaterials are a promising support for various metallic (Au, Ag, Pt, etc.) nanoparticles (NPs) used in heterogeneous catalysis [ 1 ]. These nanohybrids have shown their efficiency in the reactions of light alkene dehydrogenation [ 2 ], methane partial oxidation [ 3 ] and dry reforming [ 4 ], hydrogen peroxide generation [ 5 ], styrene production [ 6 ], and many others [ 7 , 8 , 9 , 10 , 11 , 12 , 13 ].…”

Section: Introductionmentioning

confidence: 99%

Synergistic Catalytic Effect of Ag and MgO Nanoparticles Supported on Defective BN Surface in CO Oxidation Reaction

et al. 2023

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Micron-sized supports of catalytically active nanoparticles (NPs) can become a good alternative to nanocarriers if their structure is properly tuned. Here, we show that a combination of simple and easily scalable methods, such as defect engineering and polyol synthesis, makes it possible to obtain Ag and MgO nanoparticles supported on defective hexagonal BN (h-BN) support with high catalytic activity in the CO oxidation reaction. High-temperature annealing in air of Mg-containing (<0.2 at.%) h-BN micropellets led to surface oxidation, the formation of hexagonal-shaped surface defects, and defect-related MgO NPs. The enhanced catalytic activity of Ag/MgO/h-BN materials is attributed to the synergistic effect of h-BN surface defects, ultrafine Ag and MgO NPs anchored at the defect edges, and MgO/Ag heterostructures. In addition, theoretical simulations show a shift in the electron density from metallic Ag towards MgO and the associated decrease in the negative charge of oxygen adsorbed on the Ag surface, which positively affects the catalytic activity of the Ag/MgO/h-BN material.

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Section: Introductionmentioning

confidence: 99%

Synergistic Catalytic Effect of Ag and MgO Nanoparticles Supported on Defective BN Surface in CO Oxidation Reaction

et al. 2023

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“…BN nanoplates can retain their atomic structure up to 1150 K [ 7 ], undergoing oxidation at high temperatures with the formation of B 2 O 3 [ 8 ]. Therefore, h−BN sheets are potentially widely used in many applications, such as long-range ultraviolet light-emitting diodes, field emitters, and polymer matrix nanocomposites operating under extreme conditions [ 9 , 10 , 11 , 12 , 13 ].…”

Section: Introductionmentioning

confidence: 99%

The Temperature Dependence of the Hexagonal Boron Nitride Oxidation Resistance, Insights from First−Principle Computations

2023

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In this work, we studied the oxidation stability of h−BN by investigating different variants of its modification by −OH, −O− and −O−O− groups using an atomistic thermodynamics approach. We showed that up to temperatures of ~1700 K, oxygen is deposited on the surface of hexagonal boron nitride without dissociation, in the form of peroxide. Only at higher temperatures, oxygen tends to be incorporated into the lattice of hexagonal boron nitride, except in the presence of defects Nv, when the embedding occurs at all temperatures. Finally, the electronic and magnetic properties of the oxidized h−BN were studied.

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Section: ■ Introductionmentioning

confidence: 99%

“…They have great potential for use in the textile industry due to their unique set of properties: low specific density, high thermal and chemical stability, biocompatibility, good adsorption capacity, enhanced photocatalytic properties, hydrophobicity, antibacterial activity, and wide band gap. Hexagonal BN NPs were reported to be highly biocompatible, , clinically safe, and widely used in cosmetics . BN NPs demonstrate antibacterial activity against a wide range of pathogens, including Escherichia coli, Pseudomonas aeruginosa, Staphylococcus epidermidis, Staphylococcus aureus, and others. , Recently, an improvement in heat and fire resistance of BN-modified cotton fabric has been reported. , The hydrophobic properties of a hybrid nanotextile material obtained by modifying an unbleached tent fabric (100% cellulose530 g/m 2 ) with two types of h -BN NPs (produced by Hammer and exfoliation methods) were demonstrated .…”

Section: Introductionmentioning

confidence: 99%

Antibacterial, UV-Protective, Hydrophobic, Washable, and Heat-Resistant BN-Based Nanoparticle-Coated Textile Fabrics: Experimental and Theoretical Insight

Permyakova

Tregubenko

Antipina

et al. 2022

ACS Appl. Bio Mater.

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The use of nanoparticles (NPs) to modify the surface of cotton fabric is a promising approach to endowing the material with a set of desirable characteristics that can significantly expand the functionality, wear comfort, and service life of textile products. Herein, two approaches to modifying the surface of hexagonal boron nitride (h-BN) NPs with a hollow core and a smooth surface by treatment with maleic anhydride (MA) and diethylene triamine (DETA) were studied. The DETA and MA absorption on the surface of h-BN and the interaction of surfacemodified h-NPs with cellulose as the main component of cotton were modeled using density functional theory with the extended Perdew−Burke−Ernzerhof functional. Theoretical modeling showed that the use of DETA as a binder agent can increase the adhesion strength of BN NPs to textile fabric due to the simultaneous hydrogen bonds with cellulose and BN. Due to the difference in zeta potentials (−38.4 vs −25.8 eV), MA-modified h-BN NPs form a stable suspension, while DETA-modified BN NPs tend to agglomerate. Cotton fabric coated with surface-modified NPs exhibits an excellent wash resistance and high hydrophobicity with a water contact angle of 135°(BN−MA) and 146°(BN− DETA). Compared to the original textile material, treatment with MA-and DETA-modified h-BN NPs increases heat resistance by 10% (BN−MA fabric) and 15% (BN−DETA fabric). Cotton fabrics coated with DETA-and MA-modified BN NPs show enhanced antibacterial activity against Escherichia coli U20 and Staphylococcus aureus strains and completely prevent the formation of an E. coli biofilm. The obtained results are important for the further development of fabrics for sports and medical clothing as well as wound dressings.

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Recent Progress in Fabrication and Application of BN Nanostructures and BN-Based Nanohybrids

Cited by 43 publications

References 341 publications

Synergistic Catalytic Effect of Ag and MgO Nanoparticles Supported on Defective BN Surface in CO Oxidation Reaction

Synergistic Catalytic Effect of Ag and MgO Nanoparticles Supported on Defective BN Surface in CO Oxidation Reaction

The Temperature Dependence of the Hexagonal Boron Nitride Oxidation Resistance, Insights from First−Principle Computations

Antibacterial, UV-Protective, Hydrophobic, Washable, and Heat-Resistant BN-Based Nanoparticle-Coated Textile Fabrics: Experimental and Theoretical Insight

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