We report a simple synthetic approach to coaxially grow transition metal oxide (TMO) nanostructures on carbon nanotubes (CNT) with ready control of phase and morphology. A thin (~4 nm) sulfonatedpolystyrene (SPS) pre-coating is essential for the deposition of transition metal based materials. This layer has abundant sulfonic groups (−SO 3 − ) that can effectively attract Ni 2+ , Co 2+ , Zn 2+ ions through electrostatic interaction and induce them via hydrolysis, dehydration and recrystallization to form coaxial (NiO, Co 3 O 4 , NiCoO 2 and ZnCo 2 O 4 ) shells and a nanosheet-like morphology around CNT. These structures possess a large active surface and enhanced structural robustness when used as electrode materials for lithium-ion batteries (LIBs) and electrochemical capacitors (ECs). As electrodes for LIBs, the ZnCo 2 O 4 @CNT material shows extremely stable cycling performance with a discharge capacity of 1068 mAh g −1 after 100 cycles at a current density of 400 mAg −1 . For EC applications, the NiCoO 2 @CNT exhibits a high capacitance of 1360 Fg −1 at current densities of 10 Ag −1 after 3000 cycles and an overall capacitance loss of only 1.4%. These results demonstrate the potential of such hybrid materials meeting the crucial requirements of cycling stability and high rate capability for energy conversion and storage devices.The ability to simply design and engineer new materials with tailor-made functionality is an important goal in materials science, and new classes of designer nanoscale materials will likely play a decisive role in the development of future technologies. Carbon nanotubes (CNTs) have received great interest following their discovery by Iijima in 1991 1 , owing to their excellent mechanical, thermal, and electrical properties 2-5 . In order to harness the exceptional properties of CNTs, one strategy is to exploit their applications and composite structures with other functional materials, such as polymers, metals and metal oxides/sulfides/nitrides/phosphides 2,3,6-11 . Within these hybrid materials, CNTs typically serve as the support while the functional components fill the cavities and/or are coated on the outer surface [2][3][4]6,9,10,[12][13][14][15][16] .Transition metal oxides (TMOs) as promising functional materials have been widely studied for catalysis applications, gas sensors, energy conversion and storage devices due to their abundance, environmental friendliness and specific physical/chemical properties 4,11,[16][17][18][19] . However, TMOs typically suffer from poor inherent electrical and ionic conductivities when applied in electrochemical devices such as lithium ion batteries (LIBs) and electro-chemical capacitors (ECs). To address the inherent limitations of TMOs, exciting progress has recently been made in hybridizing TMOs with a conductive matrix 5,[20][21][22][23][24] . In particular, hierarchical assembly of TMO nanosheets