Recent progress of heterogeneous catalysts for transfer hydrogenation under the background of carbon neutrality

Chen, Guangyu; Ma, Jun; Gong, Wanbing; Li, Jiayi; Li, Zheyue; Long, Ran; Xiong, Yujie

doi:10.1039/d3nr05207a

Nanoscale

2024

DOI: 10.1039/d3nr05207a

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Recent progress of heterogeneous catalysts for transfer hydrogenation under the background of carbon neutrality

Guangyu Chen,

Jun Ma,

Wanbing Gong

et al.

Abstract: This review summarizes the recent advances of heterogeneous catalysts for catalytic transfer hydrogenation using CO2-derived formic acid and methanol as the hydrogen sources.

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Cited by 6 publications

References 204 publications

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Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Joshi,

A S

et al. 2024

Chemistry An Asian Journal

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Herein, we report an inexpensive first‐row transition metal Ni heterogeneous catalytic system for the Csp3‐mono alkylation of fluorene using alcohols as alkylating agents via borrowing hydrogen strategy. The catalytic protocol displayed versatility with high yields of the desired products using various types of primary alcohols, including aryl/hetero aryl methanols, and aliphatic alcohols as alkylating agents. The catalyst Ni NPs@N‐C was synthesized via high‐temperature pyrolysis strategy, using ZIF‐8 as the sacrificial template. The Ni NPs@N‐C catalyst was characterized by XPS, HR‐TEM, HAADF‐STEM, XRD and ICP‐MS. The catalyst is stable even in the air at room temperature, displayed excellent activity and could be recycled 5 times without appreciable loss in its activity.

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Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Joshi,

A S

et al. 2024

Chemistry An Asian Journal

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Preparation of catalyst for CO2 hydrogenation reaction based on the idea of element sharing and preliminary exploration of catalytic mechanism

Jia,

Du,

et al. 2024

Environ Sci Pollut Res

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Pd Nanocatalysts supported on hollow carbon spheres for heck reaction: Void-confinement effect with varying space size in liquid-phase processes

Ma,

Yang,

et al. 2024

Applied Catalysis O: Open

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Recent progress of heterogeneous catalysts for transfer hydrogenation under the background of carbon neutrality

Abstract: This review summarizes the recent advances of heterogeneous catalysts for catalytic transfer hydrogenation using CO2-derived formic acid and methanol as the hydrogen sources.

Cited by 6 publications

References 204 publications

Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Preparation of catalyst for CO2 hydrogenation reaction based on the idea of element sharing and preliminary exploration of catalytic mechanism

Pd Nanocatalysts supported on hollow carbon spheres for heck reaction: Void-confinement effect with varying space size in liquid-phase processes

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Recent progress of heterogeneous catalysts for transfer hydrogenation under the background of carbon neutrality

Abstract: This review summarizes the recent advances of heterogeneous catalysts for catalytic transfer hydrogenation using CO2-derived formic acid and methanol as the hydrogen sources.

Cited by 6 publications

References 204 publications

Supported Nickel Nanoparticles as Catalyst in Direct sp3 C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Supported Nickel Nanoparticles as Catalyst in Direct sp3 C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Preparation of catalyst for CO2 hydrogenation reaction based on the idea of element sharing and preliminary exploration of catalytic mechanism

Pd Nanocatalysts supported on hollow carbon spheres for heck reaction: Void-confinement effect with varying space size in liquid-phase processes

Contact Info

Product

Resources

About

Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Supported Nickel Nanoparticles as Catalyst in Direct sp³ C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent