Recent Trends in Metal Alkoxide Chemistry

Mehrotra, R. C.; Singh, Anirudh

doi:10.1002/9780470166475.ch4

Cited by 103 publications

(39 citation statements)

References 506 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Equimolar reactions of Zr{Al(OPr i ) 4 } 2 Cl 2 and Zr{Nb (OPr i ) 6 } 2 Cl 2, respectively, with KNb(OPr i ) 6 and KAl (OPr i ) 4 in benzene afford heteronuclear isopropoxidechloride derivatives: …”

Section: Resultsmentioning

confidence: 99%

“…25 cm 3 ) of Zr{Al(OPr i ) 4 } 2 Cl 2 (2.79 g, 4.04 mmol) was added slowly a suspension of KNb(OPr i ) 6 [prepared from potassium (0.16 g, 4.09 mg atom) and Nb(OPr i ) 6 (1.57 g, 4.04 mmol)]. The reaction mixture was stirred at room temperature for ca.…”

Section: New Heteronuclear Complexes Of Zirconium(iv)mentioning

confidence: 99%

“…The chelating ability of the Zr 2 (OPr i ) À 9 (ligand has been widely exploited during the past decade in the development of the impressive heterometallic alkoxide chemistry of main group-, transition-, and lanthanide-elements [3][4][5][6][7][8].…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Synthesis and characterization of a new class of heteronuclear derivatives of zirconium(IV)

Sharma

Singh

Mehrotra

2005

Transition Met Chem

Self Cite

View full text Add to dashboard Cite

Reactions of Zr{Al(OPr i ) 4 } 2 Cl 2 or Zr{Nb(OPr i ) 6 } 2 Cl 2 with KNb(OPr i ) 6 /KAl(OPr i ) 4 and diethanolamines RN(CH 2 CH 2 OH) 2 [R ¼ H(L H H 2 ), Me(L Me H 2 ), and Ph(L Ph H 2 )] in the presence of two equivalents of Et 3 N yield interesting hetero(bi-and tri-) nuclear derivatives (1)-(8). All of these new derivatives have been characterized by elemental analyses, molecular weight measurements, and spectroscopic studies.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: New Heteronuclear Complexes Of Zirconium(iv)mentioning

confidence: 99%

See 1 more Smart Citation

Synthesis and characterization of a new class of heteronuclear derivatives of zirconium(IV)

Sharma

Singh

Mehrotra

2005

Transition Met Chem

Self Cite

View full text Add to dashboard Cite

show abstract

“…One of the most attractive features of the sol-gel process is the possibility to shape the resulting material into desired forms such as fiber, film and monodispersed powder. Several steps and conditions are applied in a sol-gel process to control the final morphology as suggested by Mehrotra and Singh [58] in Figure 4.…”

Section: Sol-gel Methodsmentioning

confidence: 99%

Synthetic Methods for Titanium Dioxide Nanoparticles: A Review

Nyamukamba¹,

Okoh²,

Mungondori³

et al. 2018

Titanium Dioxide - Material for a Sustainable Environment

View full text Add to dashboard Cite

Titanium dioxide (TiO 2 ) semiconductor nanoparticles are one kind of important and promising photocatalysts in photocatalysis because of their unique optical and electronic properties. Their properties, which are determined by the preparation method, are very crucial in photocatalysis. In this chapter, an overview was carried out on the different methods that are used or have been used to prepare titanium dioxide nanoparticles. There are various methods that can be used to synthesize TiO 2 and the most commonly used methods include sol-gel process, chemical vapor deposition (CVD) and hydrothermal method among others. This review will focus on selected preparation methods of titanium dioxide photocatalyst.

show abstract

“…In the synthesis of such heterobimetallic compounds, metalloligands, i.e., homometallic complexes of polyhydroxy ligands containing at least one free or coordinated OH group have played an important role [2,3]. Furthermore, deprotonated form of these ligands act both as bridging and chelating ligands to afford complexes with structural diversity.…”

Section: Introductionmentioning

confidence: 99%