“…17,19,20 A detailed inspection of the spectra shows that the band maximum slightly shifts towards higher energies (DE p ¼ 36 meV) with increasing excitation intensities from 0.1 to 55.7 mW cm À2 (i.e., 13 meV per decade of exciting intensity). The magnitude of the observed blue shift is typical for ternary and quaternary chalcogenide compounds such as TlInS 2 , 14 Tl 2 InGaS 4 , 21 HgInGaS 4 , 22 CuIn 1Àx Ga x Se 2 , 23 respective values of which were 20, 17, 20, 15 meV, respectively.…”