Recyclable Surfaces for Amine Conjugation Chemistry via Redox Reaction

Choi, Inseong; Bae, Se Won; Yeo, Woon‐Seok

doi:10.1002/bkcs.11079

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2019

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“…A trimethyl lock quinone (TLQ) moiety was originally developed by modifying Cohen's model for oxidative phosphorylation . The TLQ moiety is particularly advantageous because of its facile intramolecular ring cyclization reaction (δ‐lactonization) that can release a reporter molecule upon reduction . In this study, we focused on new TLQ reporter molecules to develop a fluorescent probe for NAD(P)H detection.…”

Section: Introductionmentioning

confidence: 99%

A Quencher‐Fluorophore‐Type Probe for Detection and Imaging of NADPH in Human Breast Cancer Cells

Kim

Bae

et al. 2019

Bulletin Korean Chem Soc

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A new fluorogenic trimethyl lock quinone (TLQ) derivative, designated as the quencher-TLQ-fluorophore-type probe (Q-TLQ-F), was developed for selective detection of nicotinamide adenine dinucleotide phosphate (NADPH). By taking advantage of the well-known facile intramolecular ring cyclization reaction (δ-lactonization) of TLQ that can release a reporter molecule upon reduction, Q-TLQ-F was successfully applied for the detection of physiological NADPH generated by glucose-6-phosphate dehydrogenase in human breast cancer MDA-MB-231 cells.

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Section: Introductionmentioning

confidence: 99%