Reductions with carbon monoxide and water in place of hydrogen. 1. Hydroformylation reaction and water gas shift reaction

CATALYSIS OF HFe3(CO)11− GRAFTED IN A HYDRATED NaY ZEOLITE IN THE WATER GAS SHIFT REACTION

“…The anionic hydride HFe3(CO) - [2][3][4][5][6] which is consistent with the more favorable thermodynamic equilibrium.7) The relatively low turnover frequency for Fe(CO)54) makes it unlikely to be a practical catalyst even under ideal conditions. However the iron carbonyl-zeolite system is an exemplary model system for the catalysis of immobilized metal carbonyls owing to the established reaction mechanism in solution2,4) and worth studying from this viewpoint.…”

Studies of the synthesis, structure, and reduction of trans-dichloro bis(2,3-dihydro-4- and 7-methylbenzo[b]thiophene)palladium(II) complexes

“…A useful review of possible mechanisms for the desulfurization of BT has been given by Gates et al (26). Reactions of la-c with CO/H,O A variety of metal complexes have been shown to catalyze the water gas shift (WGS) of CO/H20 to CO, and Hz under very moderate conditions (27)(28)(29)(30)(31)(32)(33)(34)(35)(36). A useful collation of recent work is given in ref.…”

Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction

“…As noted above, metalloform'_tes are proposed intermediates in the catalytic decomposltiom of formate and formic acid formed as per reactions (8) and (9). The general reactions for the_je decornpositions can be written as In reactions (21) and (22).…”