Reductive Dehydration of Ethanol: A New Route Towards Alkanes

Цодиков, М. В.; Yandieva, F. A.; Kugel, V. Ya.; Chistyakov, A. V.; Гехман, А. Е.; Моисеев, И. И.

doi:10.1007/s10562-007-9347-7

Cited by 21 publications

(10 citation statements)

References 13 publications

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“…The assembling of higher alkanes in very low yields from ethanol was described by Tsodikov et al . under catalysis using intermetallic hydrides with different hydrogen contents at 350 °C . Alkane assembling was described also by d'Itri et al ., who studied the conversion of dichlorodifluoromethane under hydrogenation using various catalysts, including Pd/C that was activated before the reaction and then heated to 250 °C to produce mainly methane, ethane and propane .…”

Section: Resultsmentioning

confidence: 79%

From Study of Catalytic Hydrogenation to Novel Ratiometric pH Indicators with Quinoline Scaffold

et al. 2017

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Catalytic hydrogenation of 2‐phenyl‐3‐hydroxyquinolin‐4(1H)‐ones afforded their 5,6,7,8‐tetrahydroquinolin‐4(1H)‐one analogues, which gained stability under acidic as well as alkaline conditions. For some 2‐(4‐aminophenyl) derivatives, unusual N‐isopropyl group assembling was observed in various solvents and therefore was studied in more details. The prepared derivatives were studied in context of their fluorescence properties. Some of them retained the dual character of fluorescent spectra as well as quantum yields similar to their non‐reduced parent compounds and thus were studied as potential ratiometric pH indicators.

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Section: Resultsmentioning

confidence: 79%

From Study of Catalytic Hydrogenation to Novel Ratiometric pH Indicators with Quinoline Scaffold

et al. 2017

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“…Depending on the selected catalyst, the reaction is conducted at temperatures ranging from 250 to 450 °C and atmospheric pressures . Details of ethanol conversion to butanol are given elsewhere . Technological development of this route is still limited and public technoeconomic assessments on the routes are scarce…”

Section: Routes Via Platform Chemicalsmentioning

confidence: 99%

“…[192][193][194][195]197 Details of ethanol conversion to butanol are given elsewhere. [192][193][194][195][196][197][198] Technological development of this route is still limited and public technoeconomic assessments on the routes are scarce. 199 Butanol can be further processed for the production of renewable jet fuel and chemicals but further research is still needed to optimize process conditions and quality of the fuel.…”

Section: Impact Of Feedstock and Selection Of The MIX Of Productsmentioning

confidence: 99%

Potential routes for thermochemical biorefineries

Haro

Ollero

Perales

et al. 2013

Biofuels Bioprod Bioref

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This critical review focuses on potential routes for the multi-production of chemicals and fuels in the framework of thermochemical biorefineries. The up-to-date research and development in this field has been limited to BTL/G (biomass-to-liquids/gases) studies, where biomass-derived synthesis gas (syngas) is converted into a single product with/without the co-production of electricity and heat. Simultaneously, the interest on biorefineries is growing but mostly refers to the biochemical processing of biomass. However, thermochemical biorefineries (multi-product plants using thermo-chemical processing of biomass) are still the subject of few studies. This scarcity of studies could be attributed to the limitations of current designs of BTL/G for multi-production and the limited number of considered routes for syngas conversion. The use of a platform chemical (an intermediate) brings new opportunities to the design of process concepts, since unlike BTL/G processes they are not restricted to the conversion of syngas in a single-reaction system.Most of the routes presented here are based on old-fashioned and new routes for the processing of coaland natural-gas-derived syngas, but they have been re-thought for the use of biomass and the multiproduction plants (thermochemical biorefinery). The considered platform chemicals are methanol, DME, and ethanol, which are the common products from syngas in BTL/G studies. Important keys are given for the integration of reviewed routes into the design of thermochemical biorefineries, in particular for the selection of the mix of co-products, as well as for the sustainability (co-feeding, CO2 capture, and negative emissions).

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“…32 It appeared that prolonged exposition of the wellknown industrial aluminium platinum catalyst Pt/g-Al 2 O 3 under an atmosphere of a reducing agent at >450 8C leads to a change in the composition of the ethanol conversion products (Fig. 2).…”

Section: Mech2ohmentioning

confidence: 99%

“…Thus, the crosscondensation of acylic and alicyclic alcohols provides a direct route to valuable alkylcycloalkanes (Scheme 8). 32 Scheme 8…”

Section: Mech2ohmentioning

confidence: 99%