Refinement of the crystal structure of 1,3,5,7-thioxo-2,4,6,8,9,10-hexathial, 1,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane, tetraphosphorus decasulfide, P4S10

Blachnik, R.; Matthiesen, J.; Müller, A.; Nowottnick, Heike; Reuter, Hans

doi:10.1524/ncrs.1998.213.14.247

Cited by 12 publications

(11 citation statements)

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“…Various reaction conditions are applied, including pyridine, toluene, CH 2 Cl 2 , CH 3 CN, THF, diglyme, xylene, CS 2, and dioxane as solvent, 0 °C to reflux as the reaction temperature, and in some cases in the presence of Al 2 O 3 (Table 1, entries 9-12), NaHCO 3 (Table 1, entries 18,19) and Et 3 N (Table 1, entry 28). The reaction is not preferentially carried out under inert atmosphere.…”

Section: Ketonesmentioning

confidence: 99%

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A Berzelius Reagent, Phosphorus Decasulfide (P₄S₁₀), in Organic Syntheses

2010

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Introduction 3419 2. Reactions of P 4 S 10 3421 2.1. Ketones 3421 2.2. Thionoesters, Dithioesters, Thionolactones, Dithiolactones, Thiolactones, and Dithiolethiones 3426 2.3. Amides and Lactams 3435 2.4. Imides 3448 2.5. Thiophenes 3451 2.6. Thiazolines, Thiazoles, and Thiazines 3454 2.7. Dithiazoles 3456 2.8. Thiadiazoles 3456 2.9. Imidazolines and Pyrimidines 3456 2.10. Alcohols 3458 2.11. PdO to PdS 3461 2.12. Reduction 3462 2.13. Nucleotides, Purines, and Pyrimidines 3463 2.14. Miscellaneous 3467 2.15. P 4 S 10 vs Lawesson's Reagent (LR) 3473 3. Conclusion 3473 4. Acknowledgments 3473 5. References 3473

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Section: Ketonesmentioning

confidence: 99%

“…X-ray diffraction, ,− mass, NMR, ,− infrared, Raman, ,− ESR, and XPS spectroscopic studies of P 4 S 10 were conducted. Additionally, solubility, sublimation, and vaporization behaviors were investigated in-depth.…”

Section: Introductionmentioning

confidence: 99%

A Berzelius Reagent, Phosphorus Decasulfide (P₄S₁₀), in Organic Syntheses

2010

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“…For sulfides where n = 4−9, more than one isomer may be prepared or at least detected spectroscopically (Figure ). Those phosphorus sulfides that are available directly from melt reactions of the elements in the proper ratios are P 4 S 3 , , α-P 4 S 7 , ,, and P 4 S 10 . ,, Small quantities of β-P 4 S 6 have also been identified in and isolated from phosphorus−sulfur melts . Another long-known and well-characterized phosphorus sulfide is α-P 4 S 5 , ,, which is obtained photochemically from CS 2 solutions of P 4 S 3 and elemental sulfur with catalytic traces of I 2 .…”

Section: 5 Phosphorus Sulfides P4s Nmentioning

confidence: 99%

Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions

Donahue

2006

Chem. Rev.

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“…Von P 4 S 10 [5] und a-P 4 S 9 [6] sind Kristallstrukturen bestimmt worden, wa È hrend die Charakterisierung von a-P 4 S 8 ausschlieûlich mit Hilfe der 31 P-NMR-Spektroskopie in Lo È sung erfolgte. 1969 fanden Meisel und Grunze [3] verschiedene Darstellungsmethoden fu È r P 4 S 9 , so auch die Entschwefelung von P 4 S 10 mit Triphenylphosphin.…”

Section: Phenylphosphineunclassified