1968
DOI: 10.1063/1.1656707
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Refractive Index of Carbon Dioxide Cryodeposit

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Cited by 76 publications
(31 citation statements)
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“…As the methane was temperature cycled (20 to 50 K) an interesting phase transformation took place. Figure 9b shows the infrared spectrum of this temperature cycled CH 4 (the thickness is uncertain but is estimated to be 9 /*m) and it is clear that the v 3 and v 4 bands have become much broader, 90 cm -l FWHM for v 3 compared to 20 cm ~l FWHM for the 20 K CH 4 , and also not as intense. The v 2 + v 4 band has also become much broader.…”
Section: Kchmentioning
confidence: 97%
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“…As the methane was temperature cycled (20 to 50 K) an interesting phase transformation took place. Figure 9b shows the infrared spectrum of this temperature cycled CH 4 (the thickness is uncertain but is estimated to be 9 /*m) and it is clear that the v 3 and v 4 bands have become much broader, 90 cm -l FWHM for v 3 compared to 20 cm ~l FWHM for the 20 K CH 4 , and also not as intense. The v 2 + v 4 band has also become much broader.…”
Section: Kchmentioning
confidence: 97%
“…As the deposit transformed to an as yet undetermined phase, it became highly scattering as seen in visible light, and also the near infrared transmission dropped 5% because of scattering. The broad and weak nature of the v 3 and v 4 bands in the new phase CH 4 are indicative of an amorphous solid. Thus, it is believed that this phase is a metastable phase that the CH 4 solid passes through as it transforms to an alternate crystalline phase from the 20 K crystalline phase as the temperature is raised.…”
Section: Kchmentioning
confidence: 97%
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“…The relationships among (1) (i:) \sin C cos C ~1~. o fe cos (C -P) cos C e + fo sin (C -P) sin C |e cos (C P) sin Ce -fo sin (C -P) cos C (35) It is often assumed that fe = fo; i.e., the compensator is perfectly dichroic, and the differences in multiple reflection effects along the two optical axes are negligible. Deviations from ideal behavior have been observed (Ref.…”
Section: <O>mentioning
confidence: 99%
“…The cryodeposit thickness was monitored using a dual-angle interference technique which is described in detail in Ref. 13. The particular technique used two, low-power.He-Ne (X = 6328 .A) laser beams which were injected into the vacuum chamber and specularly reflected from the Ge substrate at two accurately measured angles.…”
Section: Low-temperature Crvodeposit Systemmentioning
confidence: 99%