The syntheses, aggregation motifs and solid-state emissions of clothespin-shaped binuclear trans-bis(salicylaldiminato)platinum(II) complexes 1-4 bearing halogen atoms (X) at the para positions of phenoxy moieties are described and compared with those of the non-substituted analog 5. Crystalline (±)-4 (X = I, polymorph B) obtained by recrystallization from benzene exhibits intense phosphorescent emission under UV irradiation at ambient temperature, while crystals of (±)-1 (X = F), (±)-2 (X = Cl), (±)-3 (X = Br) and (±)-4 (X = I, polymorph A), obtained from poor solvents including hexanes, are less emissive under the same conditions. The emission intensities of these crystals increase in the order of (±)-4 (B) > (±)-5 > (±)-1- [a] 3562 platinum(II) complexes bearing halogen functionalities, with a focus on a mechanistic rationale for the specific emission enhancements observed.Scheme 2. Clothespin-shaped platinum(II) complexes 1-5 (R-form).