The membrane electrode
assembly (MEA) is considered as the center of the polymer electrolyte
membrane fuel cell (PEMFC); a solid electrolyte membrane is an indispensable
component of MEA. For membrane research and development, reducing
ohmic resistance while improving mechanical stability is a challenge.
Using short-side-chain (SSC) Aquivion perfluorosulfonic acid (PFSA)
dispersion and considering the theory of coordination networks, the
conductivity of the Aquivion polymer electrolyte membrane is improved
by incorporating a highly proton-conductive and economical three-dimensional
MOF {[(Me2NH2)3(SO4)]2[Zn2(ox)3]}
n
. The proton conductivity of the 1 wt % MOF-1/Aquivion composite
membrane was improved by 13% compared to that of the pristine Aquivion
membrane, 2 times that of Nafion and 1.5 times that of the MOF-1/Nafion
composite. The water uptake and the ion-exchange capacity values are
measured to analyze the fundamental properties of the membranes, and
physical characterization techniques are also used.