The crossover innovation springing up in emerging technologies has drawn wide attention from scholars. Innovation network, as an effective way for major innovation-driven entities towards less relevant risks and higher efficiency, can significantly affect the crossover innovation performance. This paper analyzes the evolution law of the innovation network of autonomous driving technology based on the Social Network Analysis (SNA) and by using the data on joint applications for invention patents of such technology during 2006–2020. Furthermore, the structural eigenvalues of the network evolution are calculated for the regression analysis of the relationship between network structure and crossover innovation performance. The empirical results show that network centrality, structural hole, and relationship intensity have a positive effect on crossover innovation performance of emerging technologies, while network clustering has a negative effect. Emerging technology enterprises should constantly improve their technological innovation ability, improve their status and influence in the innovation network, establish cooperation with appropriate innovation partners, further expand their own technical knowledge fields, and obtain innovation resources by optimizing the network structure so as to enhance the crossover innovation performance.