This contribution reports on a shell-model study of nuclei in the 132Sn region employing a realistic effective interaction derived from the CD-Bonn nucleon-nucleon potential renormalized through the use of the Vlow−k approach. We shall focus on some selected results for nuclei with a few valence particles and/or holes with respect to 132Sn, namely Sn isotopes with N > 82 and 130Te, which have, in part, been discussed in previous papers. Results are compared with experiments, and predictions that may provide guidance to future experiments are also discussed. It is the aim of this contribution to underline the importance of studying 132Sn neighbours to acquire a deep understanding of nuclear structure, that may be very useful also in other physics fields, and to show that the realistic shell model is a very effective tool to conduct these studies.