“…It is known that the intensity ratio between the magnetic dipole and electric dipole transitions can be an indicator of the symmetry site of the lanthanide cation inside the structure. For compound 2, the integrated area of the 4 G 5/2 → 6 H 9/2 band is larger than that of the 4 G 5/2 → 6 H 5/2 band, indicating certain asymmetry in the Sm III coordination environment [37][38][39] (the symmetry point group of the coordination polyhedron of 2 does not present an inversion symmetry).…”
A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (DppeO2) as a O-coordinated ligand through the phosphoryl group to the lanthanide(III) cations and structurally, magnetically and optically...
“…It is known that the intensity ratio between the magnetic dipole and electric dipole transitions can be an indicator of the symmetry site of the lanthanide cation inside the structure. For compound 2, the integrated area of the 4 G 5/2 → 6 H 9/2 band is larger than that of the 4 G 5/2 → 6 H 5/2 band, indicating certain asymmetry in the Sm III coordination environment [37][38][39] (the symmetry point group of the coordination polyhedron of 2 does not present an inversion symmetry).…”
A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (DppeO2) as a O-coordinated ligand through the phosphoryl group to the lanthanide(III) cations and structurally, magnetically and optically...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.