2023
DOI: 10.1039/d3ja00102d
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Resolving isobaric interference in the determination of Nd isotopes using laser ionisation mass spectrometry towards atom percent fission measurements

Namitha Janardhanan,
Ujjwal Kumar Maity,
M. Joseph
et al.

Abstract: Use of LIMS for determination of Nd in the presence of Sm.

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“…A problem with 148 Nd is an isobaric interference with 148 Sm, which generally requires chemical separation prior to mass spectrometric measurement. A study by Janardhanan et al 176 examined the potential for direct measurement by LIMS. This involved tuning laser parameters to generate NdO + while leaving Sm as an elemental ion which eliminated the isobaric interference.…”
Section: Isotope Analysismentioning
confidence: 99%
“…A problem with 148 Nd is an isobaric interference with 148 Sm, which generally requires chemical separation prior to mass spectrometric measurement. A study by Janardhanan et al 176 examined the potential for direct measurement by LIMS. This involved tuning laser parameters to generate NdO + while leaving Sm as an elemental ion which eliminated the isobaric interference.…”
Section: Isotope Analysismentioning
confidence: 99%