During the initial period of straw return, a suitable straw return technology can lay the foundation for long-term soil fertility improvement. This study focused on the issues of backward straw return technology and blind fertilizer application in the southern part of the maize-producing area in the Northeast Plain of China. In this study, two straw return modes (2-year no-tillage straw cover + 1-year deep loosening and burying straw returning mode, NPT; 3-year rotary tillage and burying straw returning mode, RT), with RT mode as a control, were combined with different N fertilizer application rates (0, 192, 240 kg/ha). The changes in soil organic carbon (SOC) and its active components (MBC, DOC, and LOC) in the 0–40 cm soil layer were analyzed, and the carbon stratification rate, carbon pool index (CPI), SOC storages of each component, and maize yield were calculated to evaluate the short-term (3-year) differences in soil organic carbon quantity and quality in order to find suitable straw return methods and nitrogen application rate combinations. The results showed that the NPT mode increased the SOC and MBC content in the 20–30 cm soil layer, with an increase of 16.2% to 37.8% and 23.0% to 50.3%, respectively, compared with the RT mode. Under the NPT mode, the carbon pool stability was higher after nitrogen fertilizer addition, with a CPI value of 10.2% to 37.8% higher in the 20–40 cm soil layer compared with the RT mode. The differences in maize yield were not significant (p < 0.05) between the nitrogen application rates of 192 kg/ha and 240 kg/ha, but the SOC storages did not show significant changes. The MBC storage had the highest value under the nitrogen application rate of 192 kg/ha. Therefore, we thought that, in the early stage of straw return, the organic carbon priming effect caused by increased microbial activity was higher under the nitrogen application rate of 192 kg/ha. Considering the aspects of not affecting maize yield and improving SOC stability, it is recommended to use the NPT mode with the application of a 240 kg/ha nitrogen fertilizer rate for straw return.