2013
DOI: 10.1016/j.reactfunctpolym.2013.01.009
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Reversible crosslinking of polymers bearing pendant or terminal thiol groups prepared by nitroxide-mediated radical polymerization

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Cited by 15 publications
(13 citation statements)
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“…203 The authors synthesized several styreneand acrylate-based copolymers bearing protected thiol groups by nitroxide-mediated radical polymerization (NMRP). Thiol deprotection followed by oxidation upon exposure to air resulted mainly in cross-linked networks via disulfide formation.…”
Section: Scheme 59 Reversible Scnp Formation Mediated By Disulfide Cmentioning
confidence: 99%
“…203 The authors synthesized several styreneand acrylate-based copolymers bearing protected thiol groups by nitroxide-mediated radical polymerization (NMRP). Thiol deprotection followed by oxidation upon exposure to air resulted mainly in cross-linked networks via disulfide formation.…”
Section: Scheme 59 Reversible Scnp Formation Mediated By Disulfide Cmentioning
confidence: 99%
“…The design of sulfur-containing polymers from functional vinyl monomers is a promising platform for providing new functional materials and unique optical polymers [15,16]. Controlled radical polymerizations of sulfur-containing vinyl monomers, such as pyridyl disulfide ethyl methacrylate [17][18][19][20], disulfide-based di(meth)acrylates [21][22][23][24], and vinyl monomers with protected thiol groups [25][26][27][28], have been employed in the production of a variety of functional polymers with well-defined structures and highly ordered architectures.…”
Section: Introductionmentioning
confidence: 99%
“…It is also possible to build in redox-cleavable sites in the polymer backbone through disulfidecontaining monomers or cross-linkers [86,[116][117][118][119][120]. In contrast to pendant disulfide bonds, the cleavage of disulfide bonds incorporated in the polymer backbone results in the (partial or total) degradation of the polymer (network).…”
Section: Page 10 Of 111mentioning
confidence: 99%
“…The thiols were recovered by reaction with TFA, after which they were converted in S-nitrosothiols, to serve as nitric oxide-releasing materials. Other examples include the synthesis of a trityl protected thiol polycarbonate [153] and the controlled radical polymerization (via NMP) of a styrenic trityl protected thiol [118].…”
Section: Thioethers and Silyl-thioethersmentioning
confidence: 99%
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