2017
DOI: 10.1016/j.poly.2017.01.062
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Reversible structural transformations of rubidium and cesium amidoboranes

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Cited by 10 publications
(6 citation statements)
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“…Both are crystalline [315]. The former crystallizes in a monoclinic system, with the space group P2 1 /c.…”
Section: Alkali and Alkaline-earth Derivatives Of Ammonia Boranementioning
confidence: 99%
“…Both are crystalline [315]. The former crystallizes in a monoclinic system, with the space group P2 1 /c.…”
Section: Alkali and Alkaline-earth Derivatives Of Ammonia Boranementioning
confidence: 99%
“…The single crystal of complex 1· (AB) 2 was serendipitously obtained in the reaction between cesium and AB in dry and degassed tetraglyme at –27 °C . Crystalline 1· (AB) 2 can be also obtained in good yield by the direct reaction between 1 and AB in 1:2 ratio (see Supporting Information for details).…”
Section: Resultsmentioning
confidence: 99%
“…Synthesis: Crystals of 1· (AB) 2 , suitable for an X‐ray diffraction experiment, were accidentally obtained as a side product of the reaction between cesium (20 mg, 1.5 mmol) and AB (10 mg, 3 mmol) in dry and degassed tetraglyme (2 mL, 10mmol) after circa 8 d at –27 °C in an argon atmosphere . In a separate experiment, AB (181 mg, 5.86 mmol) was dissolved in dry and degassed tetraglyme (649 mg, 2.92 mmol) at 45 °C and the Schlenk flask was left cooling to room temperature overnight.…”
Section: Methodsmentioning
confidence: 99%
“…% H 2 ) and cesium (CsAB, CsNH 2 BH 3 , 3.1 wt. % H 2 ) amidoboranes were synthesized for the first time in [261,262]. When these amidoboranes are heated, they undergo a phase transition.…”
Section: Monometallic Amidoboranesmentioning
confidence: 99%