Review: Recent advances of one-dimensional coordination polymers as catalysts

Abstract

LIST OF ABBREVIATIONS0D = zero-dimensional 1,4-DHPs = 1,4-dihydropyridine 1D = one-dimensional 2,4-DNP = 2,4-nitrophenol 2D = two-dimensional 2L-H2asp = N-(2-pyridylmethyl)-L-aspartic acid 3D = three-dimensional 3L-val = N-(3-pyridylmethyl)-L-valine aq. = aqueous bbbi = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole) bbmb = 1,2-bis((1H-benzo[d][1,2,3]triazol-1-yl)methyl)benzene bdob = 1,4-bis(4,5-dihydro-2-oxazolyl)benzene bipy = 4,4'-bipyridine bm = benzimidazole [(bmim)(BF4)] = 1-butyl-3-methylimidazolium tetrafluoroborate BMPyr = 1-butyl-1-methylpyrrolidinium btSe = benzene-1,2,4,5-tetraselenolate btt = benzene-1,2,4,5-tetrathiol CP = coordination polymer CR = Congo Red Cy = cyclohexane dfbi = 1,1'-(9,9-dimethyl-9H-fluorene-2,7-diyl)bis(1H-imidazole) D-H2pen = D-penicillamine DMF = N,N-dimethylformamide DMSO = Dimethylsulfoxide dped = 1,2-bis(diphenylphosphino)ethane dioxide dpppda = 1,4-N,N,N′,N′-tetra(diphenylphosphanylmethyl) benzene diamine ee = enantiomeric excess ESI-MS = electrospray ionization mass spectrometry EtOH = ethanol FTIR = Fourier-transform infrared spectroscopy Hbmmp = 4-ethyl-2,6-bis((E)-((3-morpholinopropyl)imino)methyl)phenol HPNP = 2-hydroxypropyl-p-nitrophenylphosphate Htbba = 4-((4-([2,2':6',2''-terpyridin]-4'-yl)benzyl)oxy)benzoic acid H2aipa = 5-acetamidoisophthalic acid H2bipa = 5-benzamidoisophthalic acid H2bpdc = 4,4'-biphenyldicarboxylic acid H2cybps = 1,2-cyclohexanediamino-N,N'-bis(3-tert-butyl-5-(4-pyridyl)salicylidene H2dtda = 3,3′′-dipropoxy-[1,1′:4′,1′′-terphenyl]-4,4′′-dicarboxylic acid H2hmb = 2-[(2-hydroxy-3-methoxyphenyl)methylideneamino]benzenesulfonic acid H2icyd = N,N'-bis-[(imidazol-4-yl)methylene]cyclohexane-1,2diamine H2ntp = 2-nitroterephthalic acid H2phba = 4-hydroxybenzoic acid H2ppd = bis(pyridin-2-ylmethylene)pyridine-2,6-dicarbohydrazide H2pydca = pyridine-2,6-dicarboxylate H2tae = 1,1,2,2-tetraacetylethane H3bes = N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid H3btc = 1,2,4-trimellitic acid H3ccb = 3-(carboxymethyl-amino)-4-chlorobenzoic acid H3cia = N-(4-carboxybenzyl) iminodiacetic acid H3dhia = 5-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)isophthalic acid H3dht = 2-(2-(4,4-dimethyl-2,6-dioxocyclo-hexylidene)hydrazinyl)terephthalic acid H3dmb = 2-[(2,3-dihydroxyphenyl)methylideneamino]benzenesulfonic acid H3tea = triethanolamine H4bccy = N,N′-bis(4-carboxysalicylidene)cyclohexanediamine H4bced = N,N'-bis(4-carboxysalicylidene)ethylenediamine H4hpd = bis(2-hydroxybenzylidene)pyridine-2,6-dicarbohydrazide H4pdada = 4,4'-((pyridine-2,6-dicarbonyl)bis(azanediyl))dibenzoic acid H4pma = pyromellitic acid H6bmt = (benzene-1,3,5-triyltris(methylene))triphosphonic acid H6nmp = nitrilotris(methylenephosphonic acid) IL = ionic liquid iPrOH = 2-propanol MB = methylene blue MeCN = acetonitrile MeOH = methanol MO = Methyl Orange MOF = metal-organic framework MW = microwave NB = nitrobenzene NMF = N-Methylformamide NTf2 = bis(trifluoromethanesulfonyl)imide PhIO = iodosobenzene pmba = 2-(2-pyridylmethyleneamino)benzenesulfonic acid PNP = paranitrophenol RhB = Rh...

Crystal structure of a novel one-dimensional zigzag chain-like cobalt(II) coordination polymer constructed from 4,4′-bipyridine and 2-hydroxybenzoate ligands

“…The design and construction of new coordination polymers (CPs) is of current interest and attracts researchers in the fields of modern structural chemistry and materials science because of their potential applications in areas such as ionexchange, catalysis, sensors, magnetism, and non-linear optics (Dzhardimalieva & Uflyand, 2017;Loukopoulos & Kostakis, 2018;Horike et al, 2020). It is well known that the construction of CPs depends on a variety of factors such as the nature of metal ions and the organic ligands, the molar ratio of the reactants, and the reaction conditions e.g.…”

A Discrete Molecule and a 1D Coordination Polymer of Cadmium(II): Preparation, Structures, and Properties of [Cd(L1)2(NO3)2(CH3OH)] and {[Cd(L2)(CH3COO)2]·(CH3OH)}∞ (L1 = (4‐Py)–CH=N–C10H6–NH2; L2 = (3‐Py)–CH=N–C10H6–N=CH–(3‐Py))

“…Coordination polymers (CPs) are one to three dimensional polymeric species formed by coordinative covalent bonds between metals or metal‐containing complexes (secondary building units) and organic linking ligands. These compounds continuously attract great attention, industrially and academically, due to their useful properties applicable to sensing, catalysis, energy storage (batteries and supercapacitors), explosive detection, photoluminescence, CO 2 capturing, and many more …”

Structural Diversity and Catalytic Properties in a Family of Ag(I)-Benzotriazole Based Coordination Compounds

“…solvent, metal(s)-ligand(s) ratio, temperature) parameters, allowing for greater understanding and control of the procedure. Since the first reports 2,3 that utilized these concepts, efforts have intensified with various one- 4,5 , two- [6][7][8][9][10] and threedimensional coordination polymers [11][12][13] being used as catalysts in a variety of reactions.…”