Due to the influence of psychological factors during sports, basketball players often change the shooting rhythm in sports, which will reduce the shooting rate and directly affect the training effect. Therefore, we need to analyze the basketball shooting process of some athletes, which is not a complete negation of traditional training methods, but a psychological analysis of some athletes’ shooting in the course of competition, so as to complement the feedback and training information after the game. With the great improvement of computer computing power, deep learning natural language processing can help people analyze and solve previously unsolvable problems in production and life. The psychological emotion of adolescence has a great influence on the study and life of middle school students. At present, the unified monitoring and analysis of the daily life of middle school students need not only a lot of manpower, but also slow speed. If the psychological problems are not found in time and feedback is given, it will cause a series of adverse effects on individual athletes. The neural network model based on deep learning can process students' daily mass text information quickly and accurately, and then give comprehensive judgment, which is a good solution. This paper applies the neural network algorithm of the Bi-LSTM model and CNN model to study the text data, and finally has 95.55% and 90.03% accuracy in the psychological analysis experiment, which provides a feasible solution to solve the batch rapid analysis of psychological changes reflected in the daily text of athletes during basketball. Some suggestions are put forward on how to strengthen and improve the psychological quality of college basketball players and their ability to bear pressure and difficulties.