Rhodium(I) indazole and indazolate complexes

Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O

“…Conductivities were measured in ca. 5 x mol dm acetone or nitromethane solutions, unless otherwise stated,…”

Reactivity of binuclear pyrazolate-bridged rhodium complexes with isocyanides. Molecular structure of [Rh2(µ-pz)I2(CNBut)2–(µ-Ph2PCH2PPh2)2]BF4(pz = pyrazolate)

“…The 'P-{ 'H) n.m.r. spectra of complexes (4), (5), (9), and (10) show complicated asymmetric multiplets, while the asymmetric complexes The 'H n.m.r. spectra show signals due to the isocyanide and dppm groups in the appropriate intensity ratios in each case.…”

“…1352 (8) 85 l( 9) 694( 9) 1047( 9) 1568 (9) 3 043(8) 3 548(8) 4 087 (9) 4 033 ( 10) 3 541 (10) 1800 (7) 2 276(8) 2 157 (8) 1570 (9) 1082 (9) 1 183( 8) 1310 (7) 1025 (8) 595 (8) 730 ( 10) 2 995 (9) 445( 9) were measured. Of 10552 independent reflections, 4 969, having I > 20(I), were considered observed and used in the analysis.…”