Robust power-law kinetic model for the autothermal reforming of glycerol over metal oxide catalysts

Oxidative steam reforming of glycerol. A review

“…Where A denotes CG, k0 is the Arrhenius-type pre-exponential factor and Ea is the apparent activation energy. The following kinetic parameters were found: k0=2.09 10 11 mol C gcat -1 min - In a subsequent study [79], the simulation of the catalytic reactor performance was done by developing a 2D pseudo-homogeneous numerical model using COMSOL Multiphysics software.…”

“…Kinetics of oxidative steam reforming of glycerinKinetic studies are useful for understanding reaction mechanisms, thereby for optimizing processes and for optimized catalyst and chemical reactor designs. Presently, the literature on kinetic modelling of OSR of glycerol is scarce research groups are the only known works that have dealt with kinetic modeling of OSR of glycerol of hydrogen production by OSR of synthetic CG (45.6 wt.% glycerol)[78,79]. Synthetic CG composition was established by the analyses of the composition of CG samples from a major Canadian biodiesel producer.…”

Enhanced Biomass-Derived Glycerol Conversion to Syngas in the CO2 Reforming Process: Influence of the Nickel Loading Method on Physicochemical Properties and Catalytic Performance

“…However, glycerol is produced significantly as a side effect in biodiesel manufacturing. − Nowadays, glycerol (C 3 H 5 (OH) 3 ) is an attractive potential substrate to produce many highly valued chemicals. Glycerol can also be applied to renewable syngas and hydrogen production by catalytically reforming techniques − like steam reforming, , dry reforming, − autothermal reforming, aqueous-phase reforming, , chemical looping reforming, , partial oxidation, supercritical water reforming, and sorption enhanced steam reforming . Dry reforming of glycerol (dry-RG) has emerged as a promising and attractive option due to its advantage in terms of converting CO 2 greenhouse gas to syngas and also production synthesis gas with H 2 /CO ratio lower than 2, which can be utilized in the Fischer–Tropsch (F–T) synthesis for producing a wide range of chemicals and liquid fuels .…”