Root dentin surface activation to improve bioceramic bonding: Ascanning electron microscopic study

Abstract

Background. Bioceramics need to interact chemically with dentin to exhibit adequate bioactivity.Proper bonding of bioceramics with dentin is of considerable importance. This study aimed to evaluatethe wettability and marginal adaptation of bioceramics after the use of surface-active agents on dentin:%0.5 cetrimide and %1 alkylbenzene sulfonate. Methods. Of ninety maxillary central incisors, 45 teeth were sectioned longitudinally with 45 roothalves randomly assigned to three groups (n=15): group I: no pre-treatment; group II: %0.5 cetrimide;group III: %1 alkylbenzene sulfonate. Then, the samples were subdivided into three subgroups (n=5):subgroup I: MTA; subgroup II: Biodentine, and subgroup III: BioRoot. A controlled-volume dropletof bioceramic material was placed on each root half, which was positioned in a dynamic contact angleanalyzer to record the static contact angle for wettability. The remaining 45 samples were decoronated;the root canals were prepared and randomly categorized, as mentioned above. The root canal surfaceswere treated, filled with the bioceramic material, transversely sectioned, and then each middle sectionwas analyzed microscopically for marginal adaptation. Statistical tests used included post hoc Tukeytests and one-way ANOVA. The level of statistical significance set at %95 (P<0.05). Results. The contact angle values and interfacial gap width values after surface pre-treatment weresignificantly lower when compared to no pre-treatment group (P<0.05). The values were significant for%0.5 cetrimide in the case of Biodentine and %1 alkylbenzene sulfonate in the case of BioRoot (P<0.05). Conclusion. The two surfactants yielded promising results for enhancing the wettability and marginaladaptation of materials to the root dentin, which is required for obtaining an adequate seal, penetration,and bond strength of bioceramics.

Adsorption mechanisms of short-chain and ultrashort-chain PFAS on anion exchange resins and activated carbon

“…A high-performance adsorption analyzer (Micromeritics 3Flex, USA) was used to measure the Brunauer–Emmett–Teller (BET) surface area of the adsorbents through N 2 adsorption at 77.3 K. The adsorbents were crushed and pressed onto carbon tape to obtain a thick layer, which was then manually polished. 25 The contact angle of the adsorbents was measured using an Ossila Contact Angle Goniometer, L2004A.…”