Ruthenium–tin complexes from the reaction of HSnPh3 with Ru3(CO)10(NCMe)2 and their reactions with bis(tri-t-butylphosphine)platinum

Synthesis of new heterometallic complexes by tin–sulfur bond cleavage of pySSnPh3 (pySH = pyridine-2-thiol) at triruthenium and triosmium centres

“…The most widely used method is the oxidative-addition of organotin hydrides and using this methodology a number of transition metal-tin clusters with intriguing structural features have been synthesized, as exemplified by the work of Adams and co-workers [15][16][17][18][19][20][21][22][23][24][25][26]. More recently other tin-element oxidative-addition reactions have been exploited, for example Gárate-Morales and Fernández-G have prepared amine-containing osmium-tin compounds via the cleavage of the nitrogen-tin bond in aminostannanes [27][28][29].…”

The reactions of Ir(CO)Cl(PPh3)2 with HSnPh3

“…The structure has a distorted octahedral arrangement of the six ligands. However, the stereochemistry B differs from that proposed by Lappert structure Sn(1) ¼ 150.68 (4) . This distortion is probably of a steric origin.…”

Ruthenium–tin cluster complexes and their applications as bimetallic nanoscale heterogeneous hydrogenation catalysts

“…Compounds 8 and 10 were converted to their all carbonyl forms 9 and Ru 3 (CO) 9 (SnPh 3 ) 3 (m-H) 3 , 5 by treatment with CO to replace the NCMe ligands. As was observed with 5, the SnPh 3 ligands in 9 can be transformed into bridging SnPh 2 ligands by mild heating and elimination of benzene to give the new compound Ru 3 (CO) 9 (m-SnPh 2 ) 2 , 11 (equation (3.5); Adams et al 2008a). Adams et al 2007c).…”

“…The yield was increased to 44 per cent and a low yield of the new compound Ru 3 (CO) 9 (m-SnPh 2 ) 3 , 6 was obtained when the reaction was performed under an atmosphere of hydrogen (equation (3.1); Adams et al 2008a). Burgess et al 1985).…”

“…Burgess et al 1985). 3 , 10 were obtained from the same reaction in CH 2 Cl 2 solvent (equation (3.4); Adams et al 2008a). Compounds 8 and 10 were converted to their all carbonyl forms 9 and Ru 3 (CO) 9 (SnPh 3 ) 3 (m-H) 3 , 5 by treatment with CO to replace the NCMe ligands.…”