Scalable synthetic method for SOFC compounds

Wain-Martin, Aritza; Morán-Ruiz, Aroa; Vidal, Karmele; Larrañaga, Aitor; Laguna‐Bercero, M. A.; Arriortúa, María Isabel

doi:10.1016/j.ssi.2017.08.021

Cited by 13 publications

(6 citation statements)

References 30 publications

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“…GNP requires a short time to produce big quantities of different compounds for SOFC fabrication 161 . A previous study reported that the process was reproducible, and the different batches have homogenous crystallite sizes with porous structures.…”

Section: Wet Chemical Methodsmentioning

confidence: 99%

“…• Ability to produce homogenous ceramic/composite powders • Ability to produce high-purity powders • High energy efficiency • Ability to produce ultrafine powders GNP requires a short time to produce big quantities of different compounds for SOFC fabrication. 161 A previous study reported that the process was reproducible, and the different batches have homogenous crystallite sizes with porous structures. In addition, the microstructure and purity were maintained during the process.…”

Section: Conventional Glycine-nitrate Processmentioning

confidence: 98%

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A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Hadi

Somalu

Osman

et al. 2021

Intl J of Energy Research

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The primary components of SOFCs are the anode, cathode, and the electrolyte. Anode is critical in achieving the effective electrochemical oxidation of fuel; thus, its performance can be improved using homogenous powder synthesized through an appropriate method. Various synthesis methods, including solidstate reaction and wet chemical methods have been used to synthesize anode materials. However, each technique has several advantages and disadvantages.Given that anode is a porous electrode, few criteria, such as high conductivity, tolerance towards carbon deposition, chemical stability, and thermal stability, must be fulfilled. Researchers also modified the existing synthesis method to improve the performance of the anode. In addition, various anode fabrication techniques including physical and colloidal deposition techniques are briefly discussed to understand their effect on the performance of the deposited layers.The aim of this review is to discuss the various anode synthesis and deposition techniques and their influence on the properties and performance of SOFCs.

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Section: Wet Chemical Methodsmentioning

confidence: 99%

Section: Conventional Glycine-nitrate Processmentioning

confidence: 98%

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

Hadi

Somalu

Osman

et al. 2021

Intl J of Energy Research

View full text Add to dashboard Cite

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“…In the case of LSF and LNF, the resulting powders were pelletized and calcined in air at 950 C for 8 h to obtain pure single phase samples. The properties (composition, morphologies, TEC and conductivities) of the primary materials used in the present study could be consulted in previous works [46].…”

Section: Synthesis and System Fabricationmentioning

confidence: 99%

SOFC cathodic layers using wet powder spraying technique with self synthesized nanopowders

Wain-Martin

Morán-Ruiz

Laguna‐Bercero

et al. 2019

International Journal of Hydrogen Energy

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Available online xxxKeywords: SOFC Wet powder spray Cathode Active layers Ball milling a b s t r a c t sIn this work, a wet powder spraying method has been investigated as a facile low cost route to deposit electrode layer on SOFC electrolyte support. A particular focus has been examining the interfacial stability of the deposited layers, and determining the influence of the thickness of the different layers, as well as the ball milling regime used to produce the electrode inks.The developed system consist of an yttria stabilized zirconia electrolyte support, a La 0.6 Sr 0.4 FeO 3 (LSF) cathode, a Sm 0.2 Ce 0.8 O 1.9 (SDC) barrier layer between the electrolyte and the cathode, and LaNi 0.6 Fe 0.4 O 3 (LNF) as a contact layer, for a future integration with the SOFC interconnector. The electrolyte supports (300 mm thickness and 9 mm diameter) supports were prepared by uniaxial pressing, while the deposition of thin barrier layers, cathode and contact layer were carried out by manual spray coating.Please cite this article as: Wain-Martin A et al., SOFC cathodic layers using wet powder spraying technique with self synthesized nanopowders, International Journal of Hydrogen Energy, https://doi.

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“…In the past few decades, unquestionable advantage was given to develop technologies for the appropriate industrial production of solid oxide fuel cells (SOFCs) [1,2]. Development of strong and sTab.…”

Section: Introductionmentioning

confidence: 99%

“…Development of strong and sTab. high-temperature structural ceramics for SOFCs is nowadays one of the very interesting research topics [1,2]. In the past few years the research was focused to reduce the operating temperature in the intermediate area (500-700 °C) and formation intermediate temperature solid oxide fuel cells (IT-SOFC) with high energy efficiency [3,4].…”

Section: Introductionmentioning

confidence: 99%

Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC

Egelja¹,

Pašalić²,

Dodevski³

et al. 2018

SCI SINTER

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Alumina/YAG composites (AYX_t) with high relative density (99.2 %TD) were successfully obtained by mixing commercial alumina powder with different volume fractions of yttrium aluminium garnet (Y 3 Al 5 O 12-YAG; 7, 14, 21 and 28). YAG was synthetized by nitrate glycine reaction in the form of precursor powder. Polycrystalline YAG powder was obtained by calcination at 950 °C for 2 h. Additionally, obtained compositions were characterized by XRD, SEM, EDX and electrochemical impedance spectroscopy. By XRPD analysis was found that the particle size of YAG powders lies in the nanometric range (being lower than 35 nm). By SEM microphotographs of composites were confirmed the formation of a conductive path consisting from mutually interconnected YAG particles. This was confirmed by the electrochemical impedance spectroscopy. The highest electrical conductivity of grain (κ g) and grain boundary (κ gb) at 700 ºC amounted to 2.22×10-2 Ω-1 cm-1 and 9.44×10-3 Ω-1 cm-1 , respectively, was measured in the composite containing 21 vol% of YAG.

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Scalable synthetic method for SOFC compounds

Cited by 13 publications

References 30 publications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

A review on the preparation of anode materials and anode films for solid oxide fuel cell applications

SOFC cathodic layers using wet powder spraying technique with self synthesized nanopowders

Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC

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