. Can. J. Chem. 54, 1388 (1976).McDonald's study of the absorption band at 3749 cm-1, due to the 0-H stretching vibration of hydroxyl groups on outgassed powdered silica, revealed substantial changes in center frequency and band area upon adsorption of Ar. The main features of these changes are accounted for here using an optical model for porous adsorbent-adsorbate systems due t o Dignam, Rao, and Roth. The possibility of using the measured change in band intensity on adsorbing an inert gas, as a general indicator of the orientational distribution of the adsorbed species responsible for the band, is noted. [Traduit par le journal]