<scp>3D</scp> printing flexible supercapacitors based on crosslinked poly (acrylic acid‐co‐vinylimidazole)

Wang, Yuyang; Auad, Marı́a L.; Beckingham, Bryan S.

doi:10.1002/eng2.12650

Cited by 4 publications

(1 citation statement)

References 35 publications

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“…Polymer-based electrolytes can be divided into three groups: (a) solid-state electrolytes (e.g., based on Nafion [ 110 ], polyaryletherketone [ 111 ]); (b) polymer gel electrolytes, which are further divided into hydrogel electrolytes (water as the solvent), e.g., systems based on polyvinyl alcohol (PVA), polyacrylamide (PAM), biopolymers (chitosan, agarose) [ 109 ], and organogel electrolytes (organic solvent is used, e.g., systems based on poly(acrylic acid-co-vinylimidazole) in ethylene glycol [ 112 ] and poly(vinylidene fluoride-co-hexafluoropropylene) in acetone [ 113 ]); and (c) polymer-ionic liquid electrolyte, which are melts (melting point below 100 °C) of organic salts consisting of highly asymmetric anions and cations distributed in a polymer matrix [ 114 , 115 ]. When developing polymer-based electrolytes, it is necessary to consider not only the value of their ionic conductivity, but also the degree of ion selectivity.…”

Section: The Most Common Electrode Components Of Printed Micro-superc...mentioning

confidence: 99%

Current Trends and Promising Electrode Materials in Micro-Supercapacitor Printing

Simonenko,

Gorobtsov

et al. 2023

Materials

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The development of scientific and technological foundations for the creation of high-performance energy storage devices is becoming increasingly important due to the rapid development of microelectronics, including flexible and wearable microelectronics. Supercapacitors are indispensable devices for the power supply of systems requiring high power, high charging-discharging rates, cyclic stability, and long service life and a wide range of operating temperatures (from −40 to 70 °C). The use of printing technologies gives an opportunity to move the production of such devices to a new level due to the possibility of the automated formation of micro-supercapacitors (including flexible, stretchable, wearable) with the required type of geometric implementation, to reduce time and labour costs for their creation, and to expand the prospects of their commercialization and widespread use. Within the framework of this review, we have focused on the consideration of the key commonly used supercapacitor electrode materials and highlighted examples of their successful printing in the process of assembling miniature energy storage devices.

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Section: The Most Common Electrode Components Of Printed Micro-superc...mentioning

confidence: 99%

Current Trends and Promising Electrode Materials in Micro-Supercapacitor Printing

Simonenko,

Gorobtsov

et al. 2023

Materials

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A Comparison of the Electrical Properties of Gel Polymer Electrolyte-Based Supercapacitors: A Review of Advances in Electrolyte Materials

Behzadi Pour,

Nazarpour Fard,

Fekri Aval

2024

Gels

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Flexible solid-state-based supercapacitors are in demand for the soft components used in electronics. The increased attention paid toward solid-state electrolytes could be due to their advantages, including no leakage, special separators, and improved safety. Gel polymer electrolytes (GPEs) are preferred in the energy storage field, likely owing to their safety, lack of leakage, and compatibility with various separators as well as their higher ionic conductivity (IC) than traditional solid electrolytes. This review covers the classification, properties, and configurations of different GPE-based supercapacitors and recent advancements that have occurred in this area of energy storage. Ionic liquid (IL)-based materials are popular GPEs for electrochemical energy storage and can be used to prepare unprecedented flexible supercapacitors due to their great IC and wide potential range. A comparative assessment of the GPEs-based supercapacitors reveals that in a majority of them, the value of specific capacitance is generally under 1000 F g−1, energy density reaches around 125 Wh kg−1, and the power density is seen to be less than 1500 W kg−1. The results of this research serve as an essential reference for upcoming scholars, and could significantly improve our comprehension of the efficacy of GPE-containing supercapacitors.

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Hydrogel Polymer Electrolytes: Synthesis, Physicochemical Characterization and Application in Electrochemical Capacitors

Gajewski,

Żyła,

Kazimierczak

et al. 2023

Gels

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Electrochemical capacitors operating in an aqueous electrolyte solution have become ever-more popular in recent years, mainly because they are cheap and ecofriendly. Additionally, aqueous electrolytes have a higher ionic conductivity than organic electrolytes and ionic liquids. These materials can exist in the form of a liquid or a solid (hydrogel). The latter form is a very promising alternative to liquid electrolytes because it is solid, which prevents electrolyte leakage. In our work, hydrogel polymer electrolytes (HPEs) were obtained via photopolymerization of a mixture of acrylic oligomer Exothane 108 with methacrylic acid (MAA) in ethanol, which was later replaced by electrolytes (1 M Na2SO4). Through the conducted research, the effects of the monomers ratio and the organic solvent concentration (ethanol) on the mechanical properties (tensile test), electrolyte sorption, and ionic conductivity were examined. Finally, hydrogel polymer electrolytes with high ionic conductivity (σ = 26.5 mS∙cm−1) and sufficient mechanical stability (σmax = 0.25 MPa, εmax = 20%) were tested using an AC/AC electrochemical double layer capacitor (EDLC). The electrochemical properties of the devices were investigated via cyclic voltammetry, galvanostatic charge/discharge, and impedance spectroscopy. The obtained results show the application potential of the obtained HPE in EDLC.

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3D printing flexible supercapacitors based on crosslinked poly (acrylic acid‐co‐vinylimidazole)

Cited by 4 publications

References 35 publications

Current Trends and Promising Electrode Materials in Micro-Supercapacitor Printing

Current Trends and Promising Electrode Materials in Micro-Supercapacitor Printing

A Comparison of the Electrical Properties of Gel Polymer Electrolyte-Based Supercapacitors: A Review of Advances in Electrolyte Materials

Hydrogel Polymer Electrolytes: Synthesis, Physicochemical Characterization and Application in Electrochemical Capacitors

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