2021
DOI: 10.1002/er.6629
|View full text |Cite
|
Sign up to set email alerts
|

CePMo 12 O 40 / TiO 2 catalysts for photocatalytic oxidation of methane to value‐added organic oxygenates

Abstract: Methane is the main component of natural gas. The effective activation of C-H bond of methane to synthesize value-added compounds under mild conditions is attractive. Compared to the most investigated noble metal catalysts (such as Au, Pd, and Rh), rare earth metal catalysts possess stronger oxidizing activity. Herein, we report the first synthesis of Ce cation-based phosphomolybdic salt (CePMo 12 O 40 ) with a simple milling method. Furthermore, CePMo 12 O 40 -based TiO 2 catalyst (CePMo/TiO 2 ) exhibited exc… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2022
2022
2023
2023

Publication Types

Select...
3

Relationship

1
2

Authors

Journals

citations
Cited by 3 publications
(1 citation statement)
references
References 36 publications
0
1
0
Order By: Relevance
“…Among these reactions, thermo-photo catalytic partial oxidation of CH 4 into high-value oxygenates such as CH 3 OH and HCOOH is booming very recently, in which the photo-induced reactive oxygen species such as OH and O 2 À play a crucial role for oxidation while thermal energy helps to activate reactants and promotes the desorption of oxygenates to regenerate active sites. 28,29,95,298 Representatively, visible-light driven thermophoto catalytic partial oxidation of CH 4 over Pt/WO 3 catalyst at 150 1C led to an enhancement in CH 4 conversion by 4.6 and 14.7 times with regards to photocatalysis and thermal catalysis, respectively. 28…”
Section: Ch 4 Oxidationmentioning
confidence: 99%
“…Among these reactions, thermo-photo catalytic partial oxidation of CH 4 into high-value oxygenates such as CH 3 OH and HCOOH is booming very recently, in which the photo-induced reactive oxygen species such as OH and O 2 À play a crucial role for oxidation while thermal energy helps to activate reactants and promotes the desorption of oxygenates to regenerate active sites. 28,29,95,298 Representatively, visible-light driven thermophoto catalytic partial oxidation of CH 4 over Pt/WO 3 catalyst at 150 1C led to an enhancement in CH 4 conversion by 4.6 and 14.7 times with regards to photocatalysis and thermal catalysis, respectively. 28…”
Section: Ch 4 Oxidationmentioning
confidence: 99%