Encyclopedia of Inorganic and Bioinorganic Chemistry 2005
DOI: 10.1002/9781119951438.eibc0194
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S ‐Donor Ligands

Abstract: The chemistry of S‐donor ligands with metal centres is reviewed with emphasis placed on the structures and redox activity of the resultant complexes. Sulfides and thiolates bind to a wide range of metal ions. The oxidation of thiolates to sulfones and sulfoxides and the structures and chemistry of metal‐thiolene complexes are detailed. Thioethers are generally poor ligands for transition metal ions but macrocylic ligands afford stable complexes. Many metalloproteins contain metal–sulfur bonds and the structure… Show more

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“…Despite the importance of Ni chemistry to materials and battery science, catalysis, inorganic chemistry, and bioinorganic chemistry, there are relatively few reports on 61 Ni Mössbauer spectroscopy. Specifically, there are tens of thousands of papers reporting the application of 57 Fe Mössbauer spectroscopy, while the 61 Ni Mössbauer literature can be counted in the dozens.…”
Section: Introductionmentioning
confidence: 99%
“…Despite the importance of Ni chemistry to materials and battery science, catalysis, inorganic chemistry, and bioinorganic chemistry, there are relatively few reports on 61 Ni Mössbauer spectroscopy. Specifically, there are tens of thousands of papers reporting the application of 57 Fe Mössbauer spectroscopy, while the 61 Ni Mössbauer literature can be counted in the dozens.…”
Section: Introductionmentioning
confidence: 99%