The preparation films have good properties in electronic devices, with an energy gap decreasing from 3.4 to 3.1ev with the increase of AgNPs. The extinction coefficient has the maximum value in the visible region. The absorption coefficient shows the highest value at 300nm for rGO: AgNPs, and it The increase of silver nanoparticle concentration increases the extinction coefficient values, similar to absorption coefficient behavior.Graphene oxide synthesis by hummers method and reduction by the green chemical method using green tea. Preparation films with reduced graphene oxide (rGO) and Silver Nanoparticles (AgNPs) by a spin coating method. The preparation films and Nanomaterial characteristics with X-Ray diffraction D has a pea at 2 11.22 . While rGO has a wider pea at 2 26.2 . The (rGO +AgNPs) films have five obvious diffraction angles. In Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX), flaky sheet (rGO), and spherical (AgNPs) with Nanosize about ~20 nm, the peaks of EDX indicated the presence of Carbon, silver, and oxygen. The energy gap was calculated from the absorbance spectrum and seemed to decrease with increasing AgNPs.