Abstract:A new first-order phase transition at T = 92 K has been detected in single crystals of ((CH,),N) MnCI, by means of several optical techniques. The phase transition displays a large thermal hysteresis, A T = 12 K. Coexistence of phases below 92 K is also detected. The sensitivity of the optical absorption of the crystal, as well as that of emission, excitation and lifetime of MnC$ units for detecting this phase transition is analysed in detail. The results are also compared with those corresponding to the P112,… Show more
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