The aim of this study is to enhance the mechanical, impact and open-hole compressive strengths of angular stitched glass/polypropylene/epoxy hybrid composites. The novelty of the study stems from the development of glass/polypropylene hybrid woven preforms and stitching these preforms at angular directions [+45°/0°/−45°/0°] using various fibres. The damages of open-hole angular stitched hybrid composites under mechanical and impact loads were compared with unstitched composites using ultrasonic C-Scan method. The angular stitching reduced the inter-ply delamination in the composite, ensured the preservation of the structural integrity and increased the absorption of impact energy depending on the stitching fibre types. Stitching caused less reduction in compressive strength of open-hole composite structures compared to unstitched composites. The performance of the stitching fibre used and its ability to compensate for the damage caused by the stitching process are critical parameters on the open-hole damage mechanism of composite structures.