Real-time gas sensors, which use chemiresistive metal oxide (MO) semiconductors, have become more important in both research and industry. Fiber optic metal oxide (MO) semiconductor sensors have so increased the utility and demand for optical sensors in a variety of military, industrial, and social applications. Fiber optic sensors’ inherent benefits of lightweight, compact size, and low attenuation were actively leveraged to overcome their primary disadvantage of expensive cost. With the growing need for quicker, more precise, and simpler gas sensing, metal oxide semiconductor gas sensors are focusing on new and novel materials at room temperature. The realization that materials with coexisting magnetic and ferroelectric orders offer up effective ways to alter magnetism using electric fields has drawn scientists from diverse areas together to research multiferroics for gas sensing applications in recent years. The chapter shall encompass a brief summary of the underlying physics related to fiber optic gas sensors and parameters involved in gas sensing, the significance of the fascinating class of metal oxide materials, and an outline of spin frustrated multiferroics for possible applications and its potential possibilities for progress in the future.