Shear viscosities of binary mixtures of acrylonitrile + cyclohexane, benzene, p-xylene, and mesitylene at 307.4 K

Yadava, R. R.; Yadava, S. S.

doi:10.1021/je00047a016

Cited by 16 publications

(5 citation statements)

References 3 publications

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“…We have studied molecular interactions in binary liquid mixtures of a polar aliphatic and a non-polar aromatic hydrocarbon molecules employing several techniques viz. estimation of excess volume [5], dipole moment measurements [6] and viscosity measurements [7]. Ultrasound velocity measurements have also been very widely used now a days to study binary [8,9] as well as ternary [10,11] liquid mixtures and solute of salts in a binary solvent system [12].…”

mentioning

confidence: 99%

Ultrasonic study on binary liquid mixtures between some bromoalkanes and hydrocarbons

Yadava

Yadav

2005

Ultrasonics

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confidence: 99%

Ultrasonic study on binary liquid mixtures between some bromoalkanes and hydrocarbons

Yadava

Yadav

2005

Ultrasonics

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“…To test the suitability of these viscosity models the GrunbergNissan equation with single disposable parameter for viscosities of liquid mixtures given below is analyzed: ln η=x 1 ln η 1 +x 2 ln η 2 +2 x 1 x 2 d Table 3 Katti and Chaudhri equation for mixture viscosity is ln η V=x 1 ln η 1 V 1 +x 2 ln η 2 V 2 +x 1 x 2 K 12 (6) where V is molar volume of the mixture, K 12 is the interaction parameter and equal to w visc /RT where w visc , R and T are interaction energy term, gas constant and experimental temperature, respectively; x 1 , x 2 and V 1 , V 2 are mole fractions and molar volumes of the components respectively. Hind -McLaughlin -Ubbelohde viscosity model is η=x 1 2 η 1 +x 2 2 η 2 +2 x 1 x 2 H 12 (7) where H 12 is the interaction parameter. The Sedgwick model of mixture viscosity is…”

Section: Resultsmentioning

confidence: 99%

“…Experimental values of mixture viscosities and the viscosities of their components are used in Eqs. (6), (7), and (8) to evaluate K 12 , H 12 and C. These values for all the systems studied are recorded in Table 3 with composition of the mixture. H 12 , C and K 12 are positive for all the mixtures and for complete concentration range with exception for ethanenitrile+benzene binary mixture where K 12 is negative at lower mole fractions and positive at higher mole fractions of hydrocarbon solvent.…”

Section: Resultsmentioning

confidence: 99%

“…Nitriles are a very important class of compounds due to their importance in organic synthesis and removal of coloring matters from petroleum hydrocarbons. However, little attention [6,7] has been given to the study of binary mixtures containing nitriles as one of the components. Binary mixtures of ethanenitrile and ethanol [8] at 298.15 K and of formic acid with ethanenitrile [9] at 303.15 K have been studied by viscosity measurements.…”

Section: Introductionmentioning

confidence: 99%

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Viscosities of binary mixtures of ethanenitrile with benzene and several substituted benzenes

Yadava

Singh²,

Bhan³

et al. 2010

Korean J. Chem. Eng.

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Viscosities (η) and densities (ρ) of five binary mixtures of ethanenitrile with benzene and several substituted benzenes viz methylbenzene, 1,4-dimethylbenzene, chlorobenzene and 1,2-dichlorobenzene have been experimentally determined at 308.15 K. Viscosity deviations (∆η) from the linear blending rule have been evaluated for all the mixtures studied. These are small with a maximum negative deviation of about 6% for binary mixture with benzene and maximum positive deviation of about 3% for mixture with 1,4-dimethylbenzene. ∆η Values are fitted into RedlichKister equation and standard deviations in ∆η values, σ (∆η) have been evaluated. The correlating performance of several viscosity models such as Grunberg -Nissan, Katti and Chaudhari, Hind-McLaughlin -Ubbelohde and Sedgwick has been evaluated. Grunberg-Nissan viscosity model is suitable for viscosities of several binary systems studied. The results are discussed in terms of molecular interactions between the components of binary mixtures.

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“…Molecular properties in liquid state are very useful in chemical analysis, thermodynamic and physical properties. A number of researcher's [1][2][3][4][5][6][7][8][9][10][11] has investigated the molecular interaction in binary and ternary mixtures. In the present paper we have computed R -Rao's number, C -Ultrasonic velocity, B -Wada's constant, ρ -Density of the solution, L f -Free length, βs -Adiabatic compressibility, RA -Relative association, hhydration number of pure liquids and it's mixtures at 2MHz frequency at a temperature of 303K.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of Acoustical Parameters of Aqueous Solution of Sodium Chloride and Potassium Chloride Using Ultrasonic Waves

Sasikumar¹

2015

IJRET

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The study of behaviour of propagation of ultrasonic waves in liquid system and solids is now rather well established as an effective means for examining certain physical properties of the materials. It is particularly well adapted to examine changes in such physical properties while they occur. The data obtained from ultrasonic propagation parameters such as ultrasonic velocity, adiabatic compressibility, molar volume, free length etc; and their variation with concentration of one of the component of the medium are useful in understanding the nature of molecular interaction in terms of physical parameters owing to the sensitivity to very low population densities at high energy states ultrasonic methods have been preferred and are reported to be complementary to other techniques like dielectric relaxation, I.R spectroscopy, N.M.R etc. Hence the author preferred to study the ultrasonic velocity and density measurement of aqueous solutions for NaCl and KCl of various concentrations. One of the important intermolecular properties of a liquid is the free length L f between the surfaces of two neighbouring molecules and in the distance covered by the propagating acoustic waves between the surfaces of the two neighbouring molecules. The non-linear variations are observed in acoustic parameters of NaCl and KCl solutions indicating the formation of complex ions. Molecular interactions can be studied through Rao's constants and Wada's constants which are constants in non interacting systems. The abrupt change observed in Rao's constant and Wada's constant shows existence of molecular interaction.

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Shear viscosities of binary mixtures of acrylonitrile + cyclohexane, benzene, p-xylene, and mesitylene at 307.4 K

Cited by 16 publications

References 3 publications

Ultrasonic study on binary liquid mixtures between some bromoalkanes and hydrocarbons

Ultrasonic study on binary liquid mixtures between some bromoalkanes and hydrocarbons

Viscosities of binary mixtures of ethanenitrile with benzene and several substituted benzenes

Evaluation of Acoustical Parameters of Aqueous Solution of Sodium Chloride and Potassium Chloride Using Ultrasonic Waves

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