Short Communication

Villena-Blanco, Milagros; Jolly, William L.

doi:10.1016/s0021-9673(01)82458-4

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1966

1988

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Cited by 5 publications

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“…Diese Stoffe wurden ohne zusätzliche Behandlung eingesetzt. S 4 N 4 war nach[8] dargestellt worden. Um Kristalle der beiden Isomeren zu erhalten, verfährt man wie folgt: In einem Schlenkrohr (ca.…”

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Metall-Komplexe mit S₄N₄ -Liganden: Die Strukturen von zwei Komplexen der Zusammensetzung [TiCl₄(S₄N₄)]₂ / Metal Complexes with S₄N₄ Ligands: The Structures of Two Complexes of Composition [TiCl₄(S₄N₄)]₂

Thewalt

Holl

1988

Zeitschrift Für Naturforschung B

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AbstractSlow reaction of TiCl4 with S4N4 in CH2Cl2/CCl4 produces a mixture of two crystalline dinuclear complexes of composition [TiCl4(S4N4)]2. Crystal data for the orange-yellow α-isomer: monoclinic, space group P21/n with a = 11.608(3) Å. b = 8.304(3) Å, c = 10.938(5) Å, β = 101.06(4)° and Z = 2. Crystal data for the red-brown β-isomer: monoclinic, space group P21/c with a = 11.220(2) Å, b = 13.868(2) Å, c = 14.839(4) Å, β = 106.18(2)° and Z = 4. Crystal structure analyses reveal that the S4N4 molecules in the α-form act as 1,3-N,N′-bonded bridging ligands and in the β-form as N-bonded monodentate ligands.