“…15,16,17,18,19,20 For the other spinel ferrites most theoretical studies have been done with LSD, GGA 8,21,22,23 or hybrid density functionals. 24 The former two approaches usually describe these materials to be half-metallic and not insulating, if no distortions are included. The reason is that the transition metal (TM) d electrons in oxides (as well as f electrons in rare earth compounds) are strongly correlated and cannot be adequately described within the standard band theory framework with such approximations as LSD or GGA, placing them too high in energy around the Fermi level.…”