Silica-supported ionic liquid as highly efficient catalyst for one-pot synthesis of acenaphtho[1,2-b]furan compounds

Silicon, due to its abundance, non‐toxicity, and cost‐effectiveness, is a critical element in the earth's crust with significant industrial applications. In organic chemistry, main group elements, and in particular silicon, are extensively utilized as versatile synthetic intermediates. Despite the current challenges associated with harsh reaction conditions and unsustainable practices in synthesizing crucial organic structural molecules, desilylation reactions have emerged as a facilitative method, offering milder conditions and operational simplicity. This review provides a comprehensive analysis of recent advancements in the synthesis of valuable organic molecules through two distinct desilylation reactions. It systematically presents the synthesis of a variety of derivatives, such as furan, alcohol, N‐heterocyclic, and ketone, highlighting the broad substrate tolerance of these reactions. This broad functional group compatibility suggests a promising future for the synthesis of a wide range of bioactive molecules, underscoring the significant potential of desilylation in contemporary organic synthesis.

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The catalytic effect of anion-exchanged supported ionic liquid on aza-Michael-type addition

Ghasemi

Kowsari

2016

Res Chem Intermed

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Silica-supported ionic liquid as highly efficient catalyst for one-pot synthesis of acenaphtho[1,2-b]furan compounds

Abstract: Some new derivatives of acenaphtho[1,2-b]furan have been synthesized efficiently by one-pot reaction of (acenaphthylen-1-yloxy)trimethylsilane, various aldehydes and isocyanides at the presence of silica-supported ionic liquid.

Cited by 5 publications

References 23 publications

ChemInform Abstract: Silica‐Supported Ionic Liquid as Highly Efficient Catalyst for One‐Pot Synthesis of Acenaphtho[1,2‐b]furan Compounds.

ChemInform Abstract: Silica‐Supported Ionic Liquid as Highly Efficient Catalyst for One‐Pot Synthesis of Acenaphtho[1,2‐b]furan Compounds.

Advancements in Desilylation Reactions for the Synthesis of Valuable Organic Molecules

The catalytic effect of anion-exchanged supported ionic liquid on aza-Michael-type addition

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