Silicic acid from tetraethyl silicate hydrolysis. Polymerization and properties

Bechtold, Matthias; Vest, Robert D.; Plambeck, Louis.

doi:10.1021/ja01019a015

Cited by 67 publications

(20 citation statements)

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“…This suggests that the polymeric particles of the TEOS may not consist of a single chain, but of long, more rigid triple chain molecules as proposed by Bechtold et a!. 39 …”

Section: Spinnabilitymentioning

confidence: 74%

Sol-Gel Glasses and their Future Applications

Sakka

1987

Transactions of the Indian Ceramic Society

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The outline of the sol-gel method for producing glasses and related materials has been described. This method makes it possible to synthesize glasses at relatively low temperatures and also prepare new glasses which could not be prepared by conventional melting techniques. Thus, this method has a great potential in applications to the synthesis of high technology materials.*Based on an invited lecture presented at

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“…This suggests that the polymeric particles of the TEOS may not consist of a single chain, but of long, more rigid triple chain molecules as proposed by Bechtold et a!. 39 …”

Section: Spinnabilitymentioning

confidence: 74%

Sol-Gel Glasses and their Future Applications

Sakka

1987

Transactions of the Indian Ceramic Society

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“…(3)) observed in the early stage of gelation for sample with ½Zr 4þ =½SO 2À 4 ¼ 2:5 is analogous to that reported by Pope and Mackenzie [8] for acid catalyzed silica gel, which was attributed to the occurrence of nearly linear aggregation process. This process can be described by the nearly linear growth model (NLGM) that combines the gelation kinetics equation proposed by Bechtold [17] and FloryÕs equation [18] for viscosity of nearly linear aggregate suspensions to yield:…”

Section: Discussionmentioning

confidence: 99%